%nprocshared=40
%mem=100000MB
%chk=a1_MD.chk
#p opt=(maxstep=10,tight) freq=noraman M06L/Def2TZVPP/fit EmpiricalDispersion=GD3 scf=xqc guess=mix nosymm

title

0 1
 Fe                 0.01291100    0.00384400   -0.00920700
 C                  1.69380800   -1.19878800    0.11624000
 C                  1.70023900   -0.23591000    1.16439700
 C                  1.68698900   -0.49999100   -1.12345900
 C                  1.69835300    1.05816900    0.57160200
 H                  1.68026000   -0.44877900    2.22024900
 C                  1.68990000    0.89480700   -0.84205400
 H                  1.65721000   -0.94791600   -2.10239100
 H                  1.68025000    1.99661800    1.09988200
 H                  1.66387400    1.68762500   -1.57040800
 C                 -1.65962700    1.04435400    0.61703400
 C                 -1.64451200   -0.25134200    1.21185200
 C                 -1.67893100    0.89444700   -0.79836000
 H                 -1.63106600    1.97785000    1.15520400
 C                 -1.65858300   -1.20111200    0.14866400
 C                 -1.67831100   -0.49784600   -1.08867900
 H                 -1.62789900   -2.27181900    0.26831100
 H                 -1.66464400   -0.94081300   -2.07033500
 H                 -1.64770319   -0.46944190    2.25938350
 C                 -1.66212423    2.03653699   -1.83129174
 H                 -0.64948638    2.29343567   -2.06252250
 H                 -2.16188908    1.71882341   -2.72246690
 H                 -2.16331980    2.89088164   -1.42657184
 C                  1.66016503   -2.72831859    0.29232048
 H                  0.64381184   -3.06097497    0.32790037
 H                  2.15899009   -3.19331854   -0.53220885
 H                  2.15431788   -2.99338760    1.20361153