Orca 5.0.1 RELEASE 1 2 3 4 14s9p3d1f 11s6p2d1f 11s6p2d1f 5s2p1d 5s5p3d1f 5s3p2d1f 5s3p2d1f 3s2p1d 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Cl Cl N N N C C C C C C C C C H H H H H H H H H H C N C H H H C N C H H H 1 1 2 2 2 3 3 3 3 3 3 3 3 3 4 4 4 4 4 4 4 4 4 4 3 2 3 4 4 4 3 2 3 4 4 4 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; Method DFT(GTOs) Exchange WB97X-D3 Correlation WB97X-D3 PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.195728 ScalDFX 0.000000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF Long-range corrected/Screened/Range-Separated Hybrid DFT is turned on Amount of maximum screened exact exchange 0.804272 Range separation parameter mu (erf(mu*r12)/r12) 0.250000 RI-approximation to the Coulomb term is turned on functions 1160 RIJ-COSX (HFX calculated with COS-X)) on IntName Clonidine_ACN_2a_OptFreq HFTyp RHF Charge 1 Mult 1 NEL 162 Dim 866 ENuc 1786.8718292084 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.003300 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 7.385e-06 Time for diagonalization 0.236 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.130 sec Total time needed 0.373 sec Method DFT(GTOs) Exchange WB97X-D3 Correlation WB97X-D3 PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.195728 ScalDFX 0.000000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF Long-range corrected/Screened/Range-Separated Hybrid DFT is turned on Amount of maximum screened exact exchange 0.804272 Range separation parameter mu (erf(mu*r12)/r12) 0.250000 RI-approximation to the Coulomb term is turned on functions 1160 RIJ-COSX (HFX calculated with COS-X)) on IntName Clonidine_ACN_2a_OptFreq HFTyp RHF Charge 1 Mult 1 NEL 162 Dim 866 ENuc 1786.1045698277 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 1 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.003300 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 7.372e-06 Time for diagonalization 0.192 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.155 sec Total time needed 0.352 sec 1 1 wB97X-D3 Opt Freq def2-TZVPP def2/J RIJCOSX TightSCF PAL8 defgrid3 TightOpt maxcore 4096 geom MaxIter 200 # MaxStep 0.1 Calc_Hess true chelpg grid 0.1 rmax 3.0 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 297.0785999999999 AuxInfo=1/0/N:14,12,13,6,7,10,11,9,8,1,2,3,5,4;27,25,26;33,31,32/E:(2,3)(4,5)(6,7)(10,11)(12,13);;/CRV:1.3,2.3,3.3,6.3,7.3,8.3,9.3;2*2.2,3.1/rA:36ClClNNNCCC3C3C3C3C3C3C3HHHHHHHHHHC2N1CHHHC2N1CHHH/rB:;;;;s3;s5s6;s3s4s5;s4;s1s9;s2s9;s10;s11;s12s13;s6;s6;s7;s7;s3;s4;s12;s13;s14;s5;;s25;s25;s27;s27;s27;;s31;s31;s33;s33;s33;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; -1699.093634547687 -1699.093688919315 -1699.093696635686 -1699.093696872284 -1699.093695328994 -1699.093694325390 -1699.093695255255 -1699.093694581458 -1699.093694462568 -1699.093693701433 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Cl Cl N N N C C C C C C C C C H H H H H H H H H H C N C H H H C N C H H H 0.447988 0.459023 0.353765 0.359789 0.371133 -0.007895 -0.002217 -0.276057 -0.194246 -0.383104 -0.386488 -0.021093 -0.025094 0.009331 0.020411 0.024338 0.022900 0.025474 -0.030138 -0.025282 0.031679 0.031089 0.033203 -0.071079 -0.118740 0.074110 0.032442 0.048030 0.047712 0.043947 -0.110820 0.032745 0.036501 0.048578 0.048998 0.049069 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Cl Cl N N N C C C C C C C C C H H H H H H H H H H C N C H H H C N C H H H 17.0272 17.0227 7.2136 7.2115 7.1964 6.0390 6.0358 5.6232 5.8889 6.0305 6.0220 6.0793 6.0897 6.1392 0.8907 0.8879 0.8946 0.8873 0.8057 0.7656 0.8621 0.8638 0.8506 0.7795 6.1127 7.1373 6.0539 0.8732 0.8744 0.8852 6.0749 7.2047 6.0525 0.8746 0.8761 0.8736 17.0000 17.0000 7.0000 7.0000 7.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 6.0000 7.0000 6.0000 1.0000 1.0000 1.0000 6.0000 7.0000 6.0000 1.0000 1.0000 1.0000 -0.0272 -0.0227 -0.2136 -0.2115 -0.1964 -0.0390 -0.0358 0.3768 0.1111 -0.0305 -0.0220 -0.0793 -0.0897 -0.1392 0.1093 0.1121 0.1054 0.1127 0.1943 0.2344 0.1379 0.1362 0.1494 0.2205 -0.1127 -0.1373 -0.0539 0.1268 0.1256 0.1148 -0.0749 -0.2047 -0.0525 0.1254 0.1239 0.1264 1.2968 1.3012 3.2524 3.2209 3.2642 3.9225 3.9116 4.1788 3.4875 4.1047 4.0417 3.9486 3.9315 3.9414 1.0016 1.0025 1.0039 1.0031 1.0296 1.0046 1.0081 1.0091 0.9937 1.0396 3.8531 3.1070 3.8523 1.0005 1.0001 1.0018 3.8309 3.0508 3.8503 0.9999 1.0008 0.9999 1.2968 1.3012 3.2524 3.2209 3.2642 3.9225 3.9116 4.1788 3.4875 4.1047 4.0417 3.9486 3.9315 3.9414 1.0016 1.0025 1.0039 1.0031 1.0296 1.0046 1.0081 1.0091 0.9937 1.0396 3.8531 3.1070 3.8523 1.0005 1.0001 1.0018 3.8309 3.0508 3.8503 0.9999 1.0008 0.9999 0.0000 0.0000 -0.0000 0.0000 -0.0000 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 -0.0000 -0.0000 -0.0000 0.0000 0.0000 -0.0000 -0.0000 -0.0000 -0.0000 0.0000 -0.0000 -0.0000 -0.0000 -0.0000 -0.0000 -0.0000 -0.0000 0.0000 0.0000 -0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 1.1727 1.1565 0.9048 1.3248 0.9525 1.2847 0.9255 0.9169 0.8959 1.3876 0.9059 0.9588 0.9988 0.9868 0.9924 0.9927 1.3178 1.2942 1.4191 1.4015 1.4122 0.9632 1.4103 0.9755 0.9732 2.9296 0.9113 0.9688 0.9685 0.9704 2.8943 0.9169 0.9672 0.9673 0.9681 0 9 1 10 2 5 2 7 2 18 3 7 3 8 3 19 4 6 4 7 4 23 5 6 5 14 5 15 6 16 6 17 8 9 8 10 9 11 10 12 11 13 11 20 12 13 12 21 13 22 24 25 24 26 26 27 26 28 26 29 30 31 30 32 32 33 32 34 32 35 1.0000000 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Cl Cl N N N C C C C C C C C C H H H H H H H H H H C N C H H H C N C H H H -0.027226 -0.022703 -0.213633 -0.211454 -0.196438 -0.038976 -0.035790 0.376777 0.111065 -0.030529 -0.021987 -0.079272 -0.089706 -0.139250 0.109316 0.112063 0.105416 0.112718 0.194278 0.234392 0.137940 0.136200 0.149366 0.220517 -0.112652 -0.137303 -0.053906 0.126780 0.125604 0.114832 -0.074866 -0.204678 -0.052549 0.125398 0.123869 0.126389 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 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