! wb97x-d3
! def2-TZVPP
! def2/J RIJCOSX GRIDX6 NOFINALGRIDX
! grid4 nofinalgrid
! scfconv7
! smallprint printgap noloewdin
! NOSOSCF
%MaxCore 8000
%output
       print[P_BondOrder_M] 1
       print[P_Mayer] 1
       print[P_basis] 2
end
%pal
    nprocs 8
end
%cpcm
    smd    true
    smdsolvent "WATER"
end
*xyz 0 1
Si  -2.4770653670   0.3366998820   0.2274580358
F    0.5247133079  -5.2016367839  -0.7417006761
O    0.5686461140   0.5996623557   1.5535128610
N    1.9153158028   2.3503956662  -0.2657756553
N    1.4344621689   3.2791922773  -1.0984567422
N    2.3278065239   4.2456930535   0.7192328438
C   -0.7970383969   0.9647612422  -0.4131005929
C    0.4823016006   0.3571756026   0.1664381721
C    1.7531731979   0.9366439248  -0.5026285060
C   -2.6197885071   0.4948619825   2.0993830389
C   -2.8351154782  -1.4393926067  -0.2860375274
C   -3.7534489358   1.4638533321  -0.5819626084
C    0.5123511145  -1.1446966417  -0.0560176000
C    0.4644335224  -1.6523406743  -1.3536395288
C    0.5750329289  -2.0436513378   1.0031490807
C    0.4689072168  -3.0159915444  -1.5963176135
C    0.5782959950  -3.4147832989   0.7796283874
C    2.4338269301   2.9416914996   0.8112022712
C    0.5233105680  -3.8766903578  -0.5179436313
C    1.7093724765   4.3909327819  -0.4665622705
H   -0.7862193660   2.0507617594  -0.2579536027
H   -0.8018485276   0.8441298743  -1.5007808920
H    1.7384058495   0.7807391494  -1.5792782831
H    2.6344644056   0.4297132880  -0.1088147580
H   -2.3811463972   1.5032029971   2.4449194326
H   -1.9656120147  -0.2010588800   2.6255491326
H   -3.6431620896   0.2825559493   2.4171503079
H   -3.8710349383  -1.6938991834  -0.0478427592
H   -2.1965952567  -2.1631475003   0.2219647997
H   -2.7051644444  -1.5818959455  -1.3602169898
H   -4.7683139734   1.1993898636  -0.2777116799
H   -3.7129356054   1.3979032936  -1.6713576306
H   -3.5954175596   2.5104429315  -0.3132423629
H    0.1220725470   1.4269623610   1.7587638863
H    0.4082608368  -0.9856790731  -2.2049406121
H    0.6107625795  -1.6909467332   2.0232549588
H    0.4266105356  -3.3985523701  -2.6074169364
H    0.6219524707  -4.1083623997   1.6090699855
H    2.8940222206   2.3939698405   1.6177855745
H    1.4544714061   5.3524065695  -0.8838199909
*