! wb97x-d3
! def2-TZVPP
! def2/J RIJCOSX GRIDX6 NOFINALGRIDX
! grid4 nofinalgrid
! scfconv7
! smallprint printgap noloewdin
! NOSOSCF
%MaxCore 8000
%output
       print[P_BondOrder_M] 1
       print[P_Mayer] 1
       print[P_basis] 2
end
%pal
    nprocs 8
end
%cpcm
    smd    true
    smdsolvent "WATER"
end
*xyz 0 1
Si  -2.5106338305   0.3022167766  -0.0403161988
F    0.7543317223  -5.2428422415   0.0164854007
O    0.3855435636   0.8068480128   1.4940223448
N    1.8721808424   2.3497681000  -0.4028447889
N    1.4470354098   3.1482496382  -1.3868995465
N    2.1722973352   4.3680124640   0.3512215564
C   -0.7857049965   0.8585200289  -0.6239638882
C    0.4439808634   0.3798337797   0.1502074399
C    1.7612207053   0.9126337062  -0.4661726025
C   -3.7136525189   1.1677184252  -1.2050041218
C   -2.8608074178   0.8628482596   1.7242614917
C   -2.7669190058  -1.5567915873  -0.1818515677
C    0.5393786132  -1.1359728538   0.1369842063
C    0.6153181291  -1.8137388240  -1.0787981452
C    0.5515466667  -1.8814976114   1.3109748119
C    0.6886838629  -3.1962545062  -1.1311724363
C    0.6228549818  -3.2682538095   1.2787602399
C    2.2915505252   3.0905578270   0.6238091254
C    0.6878302502  -3.9013058056   0.0559269901
C    1.6498549561   4.3404290384  -0.8884280706
H   -0.7995735365   1.9554926301  -0.6388163568
H   -0.6928714484   0.5733327858  -1.6761874393
H    1.8574035921   0.6172547015  -1.5091042626
H    2.6091752805   0.4913971551   0.0745702987
H   -3.6051239443   2.2536958605  -1.1649831210
H   -4.7504280923   0.9350753691  -0.9526670040
H   -3.5555187586   0.8630558605  -2.2418440514
H   -2.2684085202   0.3186941795   2.4607318437
H   -3.9125101459   0.6997023791   1.9707935815
H   -2.6639004075   1.9287931738   1.8600405637
H   -2.1571104358  -2.1195539840   0.5257197679
H   -2.5279668176  -1.9198240470  -1.1830158880
H   -3.8124221204  -1.8075679895   0.0142972083
H   -0.1025231344   1.6349600916   1.5411627379
H    0.6051767851  -1.2693348700  -2.0147882473
H    0.4916815351  -1.3931327722   2.2724614496
H    0.7425872035  -3.7133678299  -2.0800367735
H    0.6244412016  -3.8425002174   2.1959388423
H    2.6943056690   2.6661807611   1.5294205932
H    1.4150049562   5.2320356674  -1.4482576002
*