! wb97x-d3
! def2-TZVPP
! def2/J RIJCOSX GRIDX6 NOFINALGRIDX
! grid4 nofinalgrid
! scfconv7
! smallprint printgap noloewdin
! NOSOSCF
%MaxCore 8000
%output
       print[P_BondOrder_M] 1
       print[P_Mayer] 1
       print[P_basis] 2
end
%pal
    nprocs 8
end
%cpcm
    smd    true
    smdsolvent "WATER"
end
*xyz 0 1
Si  -3.2340441600  -0.1514216279  -0.1361648907
F    2.3506483691  -3.8018746079   0.6914158776
O   -0.7657586149   1.5673453737   0.9207795109
N    1.7151592991   2.0045675180  -0.6150073829
N    2.7512627960   1.3044213876  -1.0857296263
N    3.3442165398   2.4257464013   0.7641656649
C   -1.8209305379   0.7091003033  -1.0754921097
C   -0.5123212435   0.9417461716  -0.3198602371
C    0.3913086704   1.8592910901  -1.1718856154
C   -4.5266649414  -0.5549322339  -1.4480896624
C   -4.0137062032   1.0037116939   1.1329848133
C   -2.6867488186  -1.7426199065   0.7057139794
C    0.2326168977  -0.3467802363  -0.0261228138
C    0.7619130729  -0.6084225811   1.2331130453
C    0.4563659790  -1.2727700230  -1.0416055869
C    1.4767366052  -1.7721015883   1.4842597142
C    1.1669448298  -2.4399392767  -0.8119004531
C    2.0811736210   2.6533431148   0.4903145393
C    1.6636700435  -2.6702171747   0.4556222953
C    3.6968296818   1.5913358739  -0.2305367137
H   -2.2062613033   1.6782421759  -1.4196259479
H   -1.6314998185   0.1461712757  -1.9930323463
H   -0.0696475667   2.8447072001  -1.2587935764
H    0.5045998926   1.4608508434  -2.1778890367
H   -4.1307316484  -1.2324486281  -2.2077362016
H   -4.8709715244   0.3448305462  -1.9631061065
H   -5.4046972201  -1.0339464950  -1.0095296751
H   -4.9455196896   0.5768352781   1.5114100223
H   -4.2583980250   1.9754878399   0.6983178663
H   -3.3667636960   1.1795299440   1.9932817068
H   -3.5540173614  -2.2652656291   1.1170463513
H   -1.9947778905  -1.5581874562   1.5283875114
H   -2.1925854662  -2.4239895330   0.0107319828
H   -1.3513343879   2.3171998548   0.7689868130
H    0.6225724050   0.0890809976   2.0461227674
H    0.0792499719  -1.0962352348  -2.0410252004
H    1.8789962165  -1.9709366898   2.4691941037
H    1.3309020610  -3.1545243734  -1.6077675162
H    1.4166657454   3.2936566319   1.0466584406
H    4.6916166519   1.1869001791  -0.3359981298
*