! wb97x-d3
! def2-TZVPP
! def2/J RIJCOSX GRIDX6 NOFINALGRIDX
! grid4 nofinalgrid
! scfconv7
! smallprint printgap noloewdin
! NOSOSCF
%MaxCore 8000
%output
       print[P_BondOrder_M] 1
       print[P_Mayer] 1
       print[P_basis] 2
end
%pal
    nprocs 8
end
%cpcm
    smd    true
    smdsolvent "WATER"
end
*xyz 0 1
Si  -0.0604766947   0.4147594497   1.4752795101
F    4.7708023584  -0.2057033861  -2.0018291424
F   -4.1989069904  -3.7598827888   0.2926413215
N   -0.5693367529   2.3821970788  -0.4290476582
N    0.4878902541   3.0293144226  -0.9179856887
N   -0.7726450295   2.2257390609  -2.5903368302
C   -0.7184433646   2.1433319487   0.9928569742
C    1.4607061262   0.1153703476   0.4241703239
C   -1.3654356717  -0.8690219238   1.0560023935
C    0.3486626620   0.4174106664   3.3010949507
C    2.7370306207   0.4144248345   0.9037463706
C   -0.9983755191  -2.1963322073   0.8157025544
C    1.3450420386  -0.3091721460  -0.9019453592
C   -2.7270522726  -0.5588575881   1.0324867100
C    3.8612794214   0.3061479871   0.0974723115
C   -1.9427990780  -3.1789689197   0.5583574328
C    2.4516151553  -0.4191068556  -1.7298833180
C   -3.6913472007  -1.5227782623   0.7741692036
C   -1.2999422990   1.8985606576  -1.4316357096
C    3.6918771728  -0.1047449896  -1.2096898445
C   -3.2762193997  -2.8185932679   0.5416110339
C    0.3189411683   2.9088116518  -2.2110667042
H   -1.7625261072   2.2923904649   1.2717702046
H   -0.1531025332   2.9143133353   1.5154945050
H    1.0914849562   1.1779101335   3.5483066348
H   -0.5414604871   0.6263584981   3.8972230341
H    0.7398333667  -0.5491944670   3.6224403361
H    2.8754963638   0.7438194172   1.9264447143
H    0.0460681157  -2.4847534872   0.8244782288
H    0.3755365857  -0.5633680596  -1.3139668271
H   -3.0665052102   0.4528759329   1.2181443349
H    4.8467217087   0.5395429565   0.4785344593
H   -1.6467769271  -4.2031149351   0.3735201759
H    2.3508653560  -0.7443499810  -2.7569219801
H   -4.7427577695  -1.2683563990   0.7558701827
H   -2.2087029559   1.3367120400  -1.2803104968
H    1.0159154921   3.3429631704  -2.9104901658
*