%nprocshared=64
%mem=40GB
%chk=ts_rhIII_H-Cp-1e.chk
#p opt=(nofreeze,ts,noeigentest,readfc,maxstep=10) geom=checkpoint guess=read freq wb97xd/genecp scrf=(iefpcm,solvent=acetonitrile)
nosymm pop=(regular,orbitals=50) optcyc=500 scfcyc=500

Title Card Required

0 2

-Rh 0
lanl2dz
F    1   1.00
      1.3500000              1.0000000
****
-C O N H 0
6-31g(d,p)
****

-Rh 0
lanl2dz