Orca 5.0.2 RELEASE 1 2 3 4 5 6 17s13p8d1f 11s6p2d1f 11s6p2d1f 11s6p2d1f 5s2p1d 14s9p3d1f 6s5p4d1f 5s3p2d1f 5s3p2d1f 5s3p2d1f 3s2p1d 5s5p3d1f 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Br O N N C C C C C C C C C C C C H H H H H H H H H H H H H H H H H H H Cl 1 2 3 3 4 4 4 4 4 4 4 4 4 4 4 4 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 6 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; Method DFT(GTOs) Exchange WB97X-D3 Correlation WB97X-D3 PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.195728 ScalDFX 0.000000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF Long-range corrected/Screened/Range-Separated Hybrid DFT is turned on Amount of maximum screened exact exchange 0.804272 Range separation parameter mu (erf(mu*r12)/r12) 0.250000 RI-approximation to the Coulomb term is turned on functions 1053 RIJ-COSX (HFX calculated with COS-X)) on IntName BROMCHLORBUTEROL_R_4 HFTyp RHF Charge 1 Mult 1 NEL 164 Dim 821 ENuc 1783.4463563417 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.003300 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 6.045e-06 Time for diagonalization 0.112 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.126 sec Total time needed 0.241 sec Method DFT(GTOs) Exchange WB97X-D3 Correlation WB97X-D3 PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.195728 ScalDFX 0.000000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF Long-range corrected/Screened/Range-Separated Hybrid DFT is turned on Amount of maximum screened exact exchange 0.804272 Range separation parameter mu (erf(mu*r12)/r12) 0.250000 RI-approximation to the Coulomb term is turned on functions 1053 RIJ-COSX (HFX calculated with COS-X)) on IntName BROMCHLORBUTEROL_R_4 HFTyp RHF Charge 1 Mult 1 NEL 164 Dim 821 ENuc 1780.4263717364 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 1 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.003300 CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 6.095e-06 Time for diagonalization 0.108 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.327 sec Total time needed 0.455 sec 1 1 wB97X-D3 TightOpt Freq def2-TZVPP def2/J RIJCOSX TightSCF defgrid3 maxcore 6144 pal nprocs 8 chelpg grid 0.1 rmax 3.0 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; 303.4981999999999 AuxInfo=1/0/N:8,9,10,12,13,6,11,15,14,7,16,5,1,36,4,3,2/E:(1,2,3)/CRV:4.3,5.3,7.3,8.3,9.3,11.3,16.4/rA:36BrON4NCCCCCCC3C3C3C3C3C3HHHHHHHHHHHHHHHHHHHCl/rB:;;;s3;s3;s2s6;s5;s5;s5;s7;s11;s11;s13;s1s12;s4s14s15;s3;s6;s6;s7;s8;s8;s8;s9;s9;s9;s10;s10;s10;s12;s13;s2;s4;s4;s3;s14;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; -3687.762288546007 -3687.762306590545 -3687.762306382954 -3687.762303720904 -3687.762299450814 -3687.762296704436 -3687.762292844754 -3687.762291322087 -3687.762290358563 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Br O N N C C C C C C C C C C C C H H H H H H H H H H H H H H H H H H H Cl 0.399358 0.303632 0.541362 0.362965 -0.188480 0.024471 -0.171518 0.035196 0.036392 0.036800 -0.124936 -0.062257 -0.029815 -0.380013 -0.348722 -0.199623 0.045084 0.035635 0.035537 0.039335 0.037669 0.024526 0.024604 0.021206 0.025663 0.039196 0.039014 0.021859 0.026157 0.021195 0.032271 -0.112743 -0.041255 -0.039956 0.044277 0.445913 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Br O N N C C C C C C C C C C C C H H H H H H H H H H H H H H H H H H H Cl 35.0027 8.3373 6.8866 7.2392 5.9921 6.1509 5.8498 6.2398 6.2672 6.2645 6.0117 6.2474 6.1690 5.9967 6.0925 5.8388 0.8235 0.8518 0.8553 0.8571 0.8835 0.8897 0.8884 0.8928 0.8827 0.8775 0.8803 0.8903 0.8822 0.8504 0.8799 0.8009 0.8313 0.8375 0.8168 17.0419 35.0000 8.0000 7.0000 7.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 6.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 17.0000 -0.0027 -0.3373 0.1134 -0.2392 0.0079 -0.1509 0.1502 -0.2398 -0.2672 -0.2645 -0.0117 -0.2474 -0.1690 0.0033 -0.0925 0.1612 0.1765 0.1482 0.1447 0.1429 0.1165 0.1103 0.1116 0.1072 0.1173 0.1225 0.1197 0.1097 0.1178 0.1496 0.1201 0.1991 0.1687 0.1625 0.1832 -0.0419 1.2698 2.0940 3.6185 3.2614 4.0163 3.8487 3.9488 3.8936 3.9043 3.9094 3.5633 3.8700 4.0950 4.0423 4.1400 3.8811 1.0246 1.0125 0.9989 0.9831 1.0086 1.0063 1.0057 1.0064 1.0033 1.0077 1.0082 1.0038 1.0028 1.0304 1.0243 1.0389 1.0372 1.0448 1.0096 1.2843 1.2698 2.0940 3.6185 3.2614 4.0163 3.8487 3.9488 3.8936 3.9043 3.9094 3.5633 3.8700 4.0950 4.0423 4.1400 3.8811 1.0246 1.0125 0.9989 0.9831 1.0086 1.0063 1.0057 1.0064 1.0033 1.0077 1.0082 1.0038 1.0028 1.0304 1.0243 1.0389 1.0372 1.0448 1.0096 1.2843 0.0000 0.0000 0.0000 0.0000 -0.0000 0.0000 0.0000 -0.0000 -0.0000 0.0000 -0.0000 -0.0000 0.0000 0.0000 -0.0000 0.0000 0.0000 0.0000 -0.0000 -0.0000 -0.0000 0.0000 -0.0000 -0.0000 -0.0000 -0.0000 0.0000 -0.0000 -0.0000 -0.0000 0.0000 -0.0000 -0.0000 0.0000 0.0000 0.0000 1.2484 1.0445 1.0007 0.8411 0.8635 0.9414 0.9438 1.2480 0.9708 0.9672 0.9919 0.9930 0.9917 0.9218 0.9888 0.9937 0.9101 1.0000 0.9792 0.9750 0.9769 0.9779 0.9765 0.9804 0.9795 0.9801 0.9745 1.2748 1.3935 1.4576 0.9581 1.5193 0.9448 1.2611 1.1112 1.2820 0 14 1 6 1 31 2 4 2 5 2 16 2 34 3 15 3 32 3 33 4 7 4 8 4 9 5 6 5 17 5 18 6 10 6 19 7 20 7 21 7 22 8 23 8 24 8 25 9 26 9 27 9 28 10 11 10 12 11 14 11 29 12 13 12 30 13 15 13 35 14 15 1.0000000 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 Br O N N C C C C C C C C C C C C H H H H H H H H H H H H H H H H H H H Cl -0.002730 -0.337263 0.113433 -0.239194 0.007851 -0.150870 0.150161 -0.239760 -0.267151 -0.264535 -0.011738 -0.247365 -0.169010 0.003340 -0.092531 0.161181 0.176514 0.148186 0.144738 0.142883 0.116519 0.110263 0.111641 0.107248 0.117328 0.122465 0.119697 0.109686 0.117805 0.149556 0.120072 0.199143 0.168698 0.162513 0.183164 -0.041939 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 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525 526 527 528 529 530 531 532 533 534 535 536 537 538 539 540 541 542 543 544 545 546 547 548 549 550 551 552 553 554 555 556 557 558 559 560 561 562 563 564 565 566 567 568 569 570 571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627 628 629 630 631 632 633 634 635 636 637 638 639 640 641 642 643 644 645 646 647 648 649 650 651 652 653 654 655 656 657 658 659 660 661 662 663 664 665 666 667 668 669 670 671 672 673 674 675 676 677 678 679 680 681 682 683 684 685 686 687 688 689 690 691 692 693 694 695 696 697 698 699 700 701 702 703 704 705 706 707 708 709 710 711 712 713 714 715 716 717 718 719 720 721 722 723 724 725 726 727 728 729 730 731 732 733 734 735 736 737 738 739 740 741 742 743 744 745 746 747 748 749 750 751 752 753 754 755 756 757 758 759 760 761 762 763 764 765 766 767 768 769 770 771 772 773 774 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