Orca 5.0.2 RELEASE 1 2 3 4 5 6 7 10s7p1d 7s4p1d 10s7p1d 14s9p5d1f 14s9p5d1f 7s4p1d 4s1p 4s3p1d 3s2p1d 4s3p1d 5s3p2d1f 5s3p2d1f 3s2p1d 2s1p 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si Si O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O O Al Al Co Cu O C H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H H 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 3 3 4 5 2 6 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 2054.633375999997 AuxInfo=1/0/N:102,101;98;97;99;100;40,46,73,84,86,65,33,67,79,56,42,49,81,83,47,50,80,87,27,52,77,82,53,90,31,91,95,37,62,30,32,78,45,38,94,74,48,85,39,76,41,93,58,59,43,88,34,36,96,89,29,28,69,60,44,92,75,66,35,71,54,51,61,70,57,64,55,72,68,63,1,21,8,25,2,20,10,22,12,23,9,24,4,26,6,3,18,15,7,19,5,11,17,14,16,13/E:;;;;;(1,2,4,5)(3,6)(7,9)(8,10)(11,12,13,14)(15,16,17,18)(19,20,21,22)(23,24)(25,26)(27,28)(29,30)(31,32)(33,34)(35,36)(37,38)(39,40)(41,42)(43,44)(45,46)(47,48)(49,50)(51,52)(53,54)(55,56)(57,58)(60,61)(64,65)(66,67)(68,69)(71,72)(73,74)(75,76)(77,78)(79,80)(81,82)(83,84)(85,86)(87,88)(89,90)(91,92)(93,94)(95,96)/CRV:;;;;;3-1,6-1,8-1,10-1,29.1,30-1,35.1,36.1/rA:134SiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiSiOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOOO3OOOOOOOOOOOO3OOOOOOOOOOOOOOOOOOOO3OOAl5Al5CoCuO4CHHHHHHHHHHHHHHHHHHHHHHHHHHHHHHHH/rB:;;;;;;;;;;;;;;;;;;;;;;;;;s12;s11s23;s5s12;s15;s4;s7;s8;s6s10;s3s6;s3s22;s3;s11;s2s8;s1;s4s8;s2;s4s10;s7s9;s5;s1;s10;s1s9;s2;s10;s5s11;s12;s9;s3s14;s13s19;s25;s13s15;s2s18;s15s20;s15s24;s14s17;s18;s13s16;s7s16;s21;s14s26;s8;s11s13;s9s18;s16s18;s6s17;s5s16;s1;s14;s4s17;s20s25;s23;s19;s25;s22;s20;s23;s20;s21;s21s24;s21;s22;s22s26;s19s23;s24;s26;s19s24;s25s26;s17;s6;s7s12;s30s56s65s74;s62s67s73s94;s62s94s98;s74s97s99;s99s100;s101;s102;s101;s102;s102;s27;s31;s32;s33;s37;s38;s40;s42;s45;s46;s47;s49;s50;s52;s53;s77;s78;s79;s80;s81;s82;s83;s84;s86;s87;s90;s91;s95;/rC:;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;;; Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 0.804000 XMuePBE 0.219520 Correlation PBE PBE beta parameter CBetaPBE 0.066725 LDAOpt PW91-LDA PostSCFGGA off Density functional embedding theory OFF NL short-range parameter 6.400000 RI-approximation to the Coulomb term is turned on functions 5488 IntName cocu_ma2_ms0 HFTyp UHF Charge 0 Mult 3 NEL 1052 Dim 1734 ENuc 45068.3898261949 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 5.000e-05 Converg. threshold II (energy diff.) 1.000e-06 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 1.000e-10 Eh TCut 1.000e-11 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-06 Eh 1-El. energy change 1.000e-03 Eh TolErr 1.000e-06 Smallest eigenvalue 2.561e-03 Time for diagonalization 0.497 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.415 sec Total time needed 0.932 sec 0 3 QMMM pbe d3bj def2-svp maxcore 1800 -16421.715941139049 2054.633375999997 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-16421.44622809 45068.38982619 -61489.83605428 -112485.21513916 50995.37908488 -32773.95956512 16352.51333703 2.00421543 526.999766871170 524.999764130494 1051.999531001665 -1292.338660094600 -38.669782938730 -1331.008443033331 2.018401 1.0 2.000000 0.018401 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 207 208 209 210 211 212 213 214 215 216 217 218 219 220 221 222 223 224 225 226 227 228 229 230 231 232 233 234 235 236 237 238 239 240 241 242 243 244 245 246 247 248 249 250 251 252 253 254 255 256 257 258 259 260 261 262 263 264 265 266 267 268 269 270 271 272 273 274 275 276 277 278 279 280 281 282 283 284 285 286 287 288 289 290 291 292 293 294 295 296 297 298 299 300 301 302 303 304 305 306 307 308 309 310 311 312 313 314 315 316 317 318 319 320 321 322 323 324 325 326 327 328 329 330 331 332 333 334 335 336 337 338 339 340 341 342 343 344 345 346 347 348 349 350 351 352 353 354 355 356 357 358 359 360 361 362 363 364 365 366 367 368 369 370 371 372 373 374 375 376 377 378 379 380 381 382 383 384 385 386 387 388 389 390 391 392 393 394 395 396 397 398 399 400 401 402 403 404 405 406 407 408 409 410 411 412 413 414 415 416 417 418 419 420 421 422 423 424 425 426 427 428 429 430 431 432 433 434 435 436 437 438 439 440 441 442 443 444 445 446 447 448 449 450 451 452 453 454 455 456 457 458 459 460 461 462 463 464 465 466 467 468 469 470 471 472 473 474 475 476 477 478 479 480 481 482 483 484 485 486 487 488 489 490 491 492 493 494 495 496 497 498 499 500 501 502 503 504 505 506 507 508 509 510 511 512 513 514 515 516 517 518 519 520 521 522 523 524 525 526 527 528 529 530 531 532 533 534 535 536 537 538 539 540 541 542 543 544 545 546 547 548 549 550 551 552 553 554 555 556 557 558 559 560 561 562 563 564 565 566 567 568 569 570 571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627 628 629 630 631 632 633 634 635 636 637 638 639 640 641 642 643 644 645 646 647 648 649 650 651 652 653 654 655 656 657 658 659 660 661 662 663 664 665 666 667 668 669 670 671 672 673 674 675 676 677 678 679 680 681 682 683 684 685 686 687 688 689 690 691 692 693 694 695 696 697 698 699 700 701 702 703 704 705 706 707 708 709 710 711 712 713 714 715 716 717 718 719 720 721 722 723 724 725 726 727 728 729 730 731 732 733 734 735 736 737 738 739 740 741 742 743 744 745 746 747 748 749 750 751 752 753 754 755 756 757 758 759 760 761 762 763 764 765 766 767 768 769 770 771 772 773 774 775 776 777 778 779 780 781 782 783 784 785 786 787 788 789 790 791 792 793 794 795 796 797 798 799 800 801 802 803 804 805 806 807 808 809 810 811 812 813 814 815 816 817 818 819 820 821 822 823 824 825 826 827 828 829 830 831 832 833 834 835 836 837 838 839 840 841 842 843 844 845 846 847 848 849 850 851 852 853 854 855 856 857 858 859 860 861 862 863 864 865 866 867 868 869 870 871 872 873 874 875 876 877 878 879 880 881 882 883 884 885 886 887 888 889 890 891 892 893 894 895 896 897 898 899 900 901 902 903 904 905 906 907 908 909 910 911 912 913 914 915 916 917 918 919 920 921 922 923 924 925 926 927 928 929 930 931 932 933 934 935 936 937 938 939 940 941 942 943 944 945 946 947 948 949 950 951 952 953 954 955 956 957 958 959 960 961 962 963 964 965 966 967 968 969 970 971 972 973 974 975 976 977 978 979 980 981 982 983 984 985 986 987 988 989 990 991 992 993 994 995 996 997 998 999 1000 1001 1002 1003 1004 1005 1006 1007 1008 1009 1010 1011 1012 1013 1014 1015 1016 1017 1018 1019 1020 1021 1022 1023 1024 1025 1026 1027 1028 1029 1030 1031 1032 1033 1034 1035 1036 1037 1038 1039 1040 1041 1042 1043 1044 1045 1046 1047 1048 1049 1050 1051 1052 1053 1054 1055 1056 1057 1058 1059 1060 1061 1062 1063 1064 1065 1066 1067 1068 1069 1070 1071 1072 1073 1074 1075 1076 1077 1078 1079 1080 1081 1082 1083 1084 1085 1086 1087 1088 1089 1090 1091 1092 1093 1094 1095 1096 1097 1098 1099 1100 1101 1102 1103 1104 1105 1106 1107 1108 1109 1110 1111 1112 1113 1114 1115 1116 1117 1118 1119 1120 1121 1122 1123 1124 1125 1126 1127 1128 1129 1130 1131 1132 1133 1134 1135 1136 1137 1138 1139 1140 1141 1142 1143 1144 1145 1146 1147 1148 1149 1150 1151 1152 1153 1154 1155 1156 1157 1158 1159 1160 1161 1162 1163 1164 1165 1166 1167 1168 1169 1170 1171 1172 1173 1174 1175 1176 1177 1178 1179 1180 1181 1182 1183 1184 1185 1186 1187 1188 1189 1190 1191 1192 1193 1194 1195 1196 1197 1198 1199 1200 1201 1202 1203 1204 1205 1206 1207 1208 1209 1210 1211 1212 1213 1214 1215 1216 1217 1218 1219 1220 1221 1222 1223 1224 1225 1226 1227 1228 1229 1230 1231 1232 1233 1234 1235 1236 1237 1238 1239 1240 1241 1242 1243 1244 1245 1246 1247 1248 1249 1250 1251 1252 1253 1254 1255 1256 1257 1258 1259 1260 1261 1262 1263 1264 1265 1266 1267 1268 1269 1270 1271 1272 1273 1274 1275 1276 1277 1278 1279 1280 1281 1282 1283 1284 1285 1286 1287 1288 1289 1290 1291 1292 1293 1294 1295 1296 1297 1298 1299 1300 1301 1302 1303 1304 1305 1306 1307 1308 1309 1310 1311 1312 1313 1314 1315 1316 1317 1318 1319 1320 1321 1322 1323 1324 1325 1326 1327 1328 1329 1330 1331 1332 1333 1334 1335 1336 1337 1338 1339 1340 1341 1342 1343 1344 1345 1346 1347 1348 1349 1350 1351 1352 1353 1354 1355 1356 1357 1358 1359 1360 1361 1362 1363 1364 1365 1366 1367 1368 1369 1370 1371 1372 1373 1374 1375 1376 1377 1378 1379 1380 1381 1382 1383 1384 1385 1386 1387 1388 1389 1390 1391 1392 1393 1394 1395 1396 1397 1398 1399 1400 1401 1402 1403 1404 1405 1406 1407 1408 1409 1410 1411 1412 1413 1414 1415 1416 1417 1418 1419 1420 1421 1422 1423 1424 1425 1426 1427 1428 1429 1430 1431 1432 1433 1434 1435 1436 1437 1438 1439 1440 1441 1442 1443 1444 1445 1446 1447 1448 1449 1450 1451 1452 1453 1454 1455 1456 1457 1458 1459 1460 1461 1462 1463 1464 1465 1466 1467 1468 1469 1470 1471 1472 1473 1474 1475 1476 1477 1478 1479 1480 1481 1482 1483 1484 1485 1486 1487 1488 1489 1490 1491 1492 1493 1494 1495 1496 1497 1498 1499 1500 1501 1502 1503 1504 1505 1506 1507 1508 1509 1510 1511 1512 1513 1514 1515 1516 1517 1518 1519 1520 1521 1522 1523 1524 1525 1526 1527 1528 1529 1530 1531 1532 1533 1534 1535 1536 1537 1538 1539 1540 1541 1542 1543 1544 1545 1546 1547 1548 1549 1550 1551 1552 1553 1554 1555 1556 1557 1558 1559 1560 1561 1562 1563 1564 1565 1566 1567 1568 1569 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37.6504 37.6870 37.7800 37.8797 37.9704 38.0692 38.1853 38.2947 38.3852 38.4310 38.5409 38.5807 38.7134 38.7700 38.9083 39.0320 39.1723 39.2721 39.3960 40.0391 40.1981 40.5452 42.8829 43.8794 44.2878 44.7485 45.2963 47.8740 48.1252 48.3887 48.4834 48.5057 48.5731 48.8191 48.9194 48.9743 49.0066 49.0558 49.0727 49.1158 49.1504 49.3045 49.3275 49.3657 49.4335 49.5713 49.6488 49.6632 50.0058 50.0959 50.1221 50.1408 50.2499 50.2557 50.5018 50.9215 51.0043 54.1862 54.4548 58.2948 58.5545 58.7084 58.7632 58.7681 58.8019 58.8076 58.9083 58.9764 59.0272 59.0863 59.1337 59.1574 59.1732 59.1844 59.2014 59.2458 59.2495 59.2823 59.3137 59.3693 59.3803 59.3883 59.4186 59.4575 59.4648 59.4971 59.5229 59.5689 59.5981 59.6175 59.6301 59.6517 59.6589 59.6829 59.7457 59.7552 59.7705 59.7866 59.8039 59.8350 59.8593 59.8798 59.9260 59.9427 59.9526 60.0411 60.0667 60.0972 60.1404 60.1734 60.1924 60.2442 60.2836 60.3141 60.3334 60.3564 60.4545 60.4720 60.5009 60.5276 60.5460 60.5930 60.6201 60.6649 60.6818 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68.6051 68.6919 68.7765 68.8274 68.8535 69.0273 69.0740 69.0844 69.1213 69.1504 69.1882 69.2267 69.2938 69.3561 69.4854 69.5661 69.6499 69.6863 69.7195 69.7309 69.7942 69.8109 69.8305 69.8651 69.8930 69.9120 69.9544 69.9613 69.9924 70.0546 70.1132 70.2167 70.2271 70.3114 70.3673 70.4192 70.5075 70.5701 70.5901 70.6458 70.7521 70.8385 70.8487 71.0170 71.1650 71.2334 71.3125 71.4274 71.4815 71.5314 71.6298 71.7013 71.7854 71.9527 72.1428 72.1788 72.2918 72.3391 72.5214 72.5989 72.9743 73.1164 73.2193 73.2364 73.3516 73.3909 73.5246 73.6356 73.7908 73.8789 73.9750 74.0777 74.2293 74.2878 74.4396 74.5368 74.6655 74.7540 74.8520 75.1017 75.2527 75.4536 75.5899 75.6687 75.7113 75.7787 75.8492 75.9008 75.9660 76.0279 76.0983 76.2172 76.2570 76.3450 76.5195 76.5891 76.6000 76.6566 76.7447 76.7828 76.8246 76.9382 76.9689 77.0746 77.2513 77.2786 77.5122 77.5575 77.6483 77.7009 77.7236 77.7490 77.8536 77.8853 77.9244 77.9621 77.9811 78.2250 78.2855 78.3367 78.5447 78.6008 78.6459 78.7104 78.7471 78.8176 79.0059 79.1438 79.1719 79.2020 79.2252 79.2579 79.4171 79.4732 79.5652 79.6753 79.8921 79.9368 88.1421 88.3538 88.6573 88.7271 88.7486 89.0358 89.0467 89.0541 89.0715 89.0905 89.2809 89.3531 89.4014 89.4157 89.5077 89.5389 89.6147 89.6404 89.7430 89.9059 89.9730 90.0293 90.0602 90.1157 90.1411 90.2057 90.5273 90.5449 90.9067 120.0527 120.4897 120.6565 121.0659 121.4042 122.0069 122.3245 144.9980 145.0521 145.0912 145.1147 145.1794 145.4738 146.1806 UP 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 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