! SP DSD-BLYP D3BJ def2-QZVPP def2-QZVPP/C def2/J TightSCF CPCM(Acetonitrile)
%cpcm
surfacetype vdw_gaussian
end
%output 
xyzfile=True 
end 
%scf 
maxiter 250 
end
%output
Print[P_Hirshfeld] = 1
end
% maxcore
3000
%pal nprocs 16
end
*xyz 0 1
C    1.39626320  -0.78938857  -0.07426958 
C    0.82299689   0.36475959  -0.39867779 
C   -0.60021602   0.75438447  -0.14313127 
C   -1.45323303  -0.29375444   0.55207543 
H    0.85848583  -1.58570542   0.42537105 
H    2.43672064  -0.98151090  -0.30158970 
H    1.42343003   1.11901025  -0.89983911 
H   -1.05782373   1.02848343  -1.09951457 
H   -0.60203345   1.68082605   0.44088373 
H   -1.05300190  -0.55027096   1.53384834 
H   -2.46919474   0.07331172   0.69541997 
H   -1.51240124  -1.21313571  -0.03191202 
*