%chk=TBHP-enol.chk
%nprocshared=32
%mem=64GB
#p opt freq wb97xd/gen scrf=(smd,solvent=dichloromethane) pseudo=read

continue calc

1 1
 C                 -1.21648200    2.75554500   -0.21822200
 C                 -1.28960800    1.47109200   -0.75500700
 C                 -2.45555100    1.04997300   -1.39249800
 C                 -3.51183800    1.95033800   -1.42564600
 C                 -3.41790900    3.23077600   -0.85389100
 C                 -2.25310800    3.67039600   -0.23595100
 C                  0.67441700    1.78080900    0.06107500
 H                 -2.54044300    0.07225300   -1.84660700
 H                 -4.43674500    1.65858000   -1.91144600
 H                 -4.27191400    3.89752200   -0.90481200
 H                 -2.15605600    4.65964300    0.19517100
 C                  2.07405900    1.57176900    0.40705800
 C                  2.89584800    2.51019400    1.00546900
 N                  2.50782500    0.34270900    0.05530300
 C                  4.22365200    2.15362600    1.24115400
 H                  2.51218800    3.48682600    1.27614900
 C                  3.77383000   -0.00053400    0.28339000
 C                  4.66727400    0.89003000    0.87510200
 H                  4.90043700    2.86161200    1.70611700
 H                  4.04449000   -1.00814400   -0.01614300
 H                  5.69285200    0.58371900    1.04273200
 N                 -0.04721400    0.86868200   -0.53440100
 O                  0.04790500    2.93165700    0.29470200
 Pd                 1.03383400   -0.92385100   -0.73350000
 O                  2.36461400   -2.34665800   -0.82545300
 O                 -0.08626700   -3.72490800    0.07678100
 C                 -0.47231500   -2.17917400   -1.63145100
 H                 -1.16932600   -1.47111500   -2.06299900
 H                  0.02617500   -2.85852200   -2.31753500
 C                 -0.68771100   -2.60068500   -0.32555800
 H                 -0.25141500   -3.89502700    1.01716600
 C                 -1.64065600   -1.96446700    0.61934800
 C                 -2.96234200   -1.74991200    0.22421300
 C                 -3.85980500   -1.15901000    1.10863900
 H                 -3.28558500   -2.05152300   -0.76718400
 C                 -2.11790700   -0.99065700    2.77480300
 C                 -3.43739000   -0.77282100    2.37788300
 H                 -4.88758200   -0.99558200    0.80190800
 H                 -1.78786800   -0.68769000    3.76307900
 H                 -4.13715900   -0.30371900    3.06198500
 C                 -1.21978000   -1.59332100    1.90231700
 H                 -0.18583700   -1.74409100    2.20264100
 C                  2.86215079   -2.48794876   -2.15864243
 C                  4.13041593   -3.36137339   -2.14337952
 H                  3.87046250   -4.36294717   -1.87103016
 H                  4.57581674   -3.36049066   -3.11627075
 H                  4.82616540   -2.96754204   -1.43223289
 C                  1.78941705   -3.15590714   -3.03879805
 H                  2.06940531   -3.07161892   -4.06807064
 H                  1.70509661   -4.18959937   -2.77560529
 H                  0.84840852   -2.67060385   -2.88425465
 C                  3.20242808   -1.09872501   -2.72949156
 H                  3.46575313   -0.43902610   -1.92926829
 H                  4.02591766   -1.18361523   -3.40739905
 H                  2.35203974   -0.70829420   -3.24843612

Pd 0
sdd
F 1 1.0
1.472 1.0
****
C H 0
6-31g(d,p)
****
O N 0
6-31+g(d,p)
****

Pd
sdd