%mem=300GB
%chk=alkene_SO2Ph.chk
#p opt freq wb97xd scrf=(solvent=diethylether) nosymm def2svp

Title Card Required

0 1
 C                  1.90698300    1.11503500    0.57580000
 H                  2.45190100    0.64460500    1.39875800
 H                  0.81764500    1.03446300    0.55738300
 C                  2.55735300    1.76312800   -0.38340200
 H                  2.09136000    2.25322400   -1.24212800
 S                  4.33315300    1.83134200   -0.37444900
 O                  4.81442000    1.11584700    0.80620900
 O                  4.78724500    1.44264600   -1.70811200
 C                  4.69058100    3.56620600   -0.15657900
 C                  4.73339400    4.09198300    1.13470200
 C                  4.92728600    4.35562900   -1.28044000
 C                  5.00791700    5.44728200    1.29820800
 H                  4.56288500    3.44290500    1.99550800
 C                  5.20183600    5.71070300   -1.10294600
 H                  4.90594100    3.90631400   -2.27468600
 C                  5.23950500    6.25350900    0.18171700
 H                  5.04770500    5.87529900    2.30158700
 H                  5.39263500    6.34319000   -1.97192500
 H                  5.45646700    7.31528800    0.31574400