%chk=c5ab-cmdb2.chk
%cpu=16
%mem=50GB
#p opt=(ts,noeigentest,calcall) wb97xd gen pseudo=read scrf=(smd,solvent=1,4-dioxane)

Title Card Required

0 1
 C                 -2.20123800   -0.18847800   -0.70236600
 C                 -0.02617100   -0.29120600   -1.05765200
 C                 -0.61809300    0.53396000   -2.02724200
 H                  0.71397000   -1.14352500   -1.43812100
 Rh                 1.54581700    0.60021000    0.13138000
 C                  2.86835600    2.34077900   -0.12379400
 C                  2.59480900    2.17721400    1.25657900
 C                  1.63506100    2.54454700   -0.81340100
 H                  3.83595400    2.23376200   -0.59474700
 C                  1.16907800    2.31499500    1.43611100
 H                  3.31636900    1.98761600    2.03831400
 C                  0.58267400    2.55951600    0.17545300
 H                  1.52366300    2.72123200   -1.87327400
 H                  0.63942200    2.21058400    2.37259700
 H                 -0.47210900    2.69447900   -0.02000900
 Cl                 1.29734600   -1.03379000    1.94687800
 O                  2.95223000   -0.69515100   -0.61330300
 C                  2.74425000   -1.89692400   -1.20797400
 O                  1.73137300   -2.06505600   -1.94694000
 O                  3.61143200   -2.77047500   -0.94146500
 Na                 3.73419100   -1.93483700    1.13246600
 H                 -0.06781700    0.99410700   -2.83706600
 O                 -3.28090900   -0.57589700   -0.01986200
 C                 -4.48525400    0.10088100   -0.16345400
 O                 -4.58122200    1.14617500   -0.76822800
 N                 -5.46776900   -0.57249600    0.46244600
 C                 -5.27425800   -1.79156200    1.23290300
 H                 -4.39620600   -2.33508600    0.89252500
 H                 -5.16444200   -1.56730900    2.30013900
 H                 -6.15203600   -2.42896500    1.09824000
 C                 -6.78517900    0.03442300    0.53479900
 H                 -7.53603900   -0.66241100    0.14945100
 H                 -7.03293300    0.28034500    1.57353500
 H                 -6.79955500    0.94418600   -0.06210900
 O                 -1.10210400   -0.74164100   -0.25584300
 C                 -1.99246900    0.62382500   -1.80483600
 H                 -2.74243100    1.17122100   -2.34839700

Rh 0
sdd
****
C H O N Cl Na 0
6-31G(d,p)
****

Rh 0
sdd