%chk=c5ab-cmda.chk
%CPU=16
%mem=50GB
#p opt=modredundant wb97xd gen scrf=(smd,solvent=1,4-dioxane) pseudo=read

Title Card Required

0 1
 C                 -2.11413649   -0.07620499    0.88978226
 C                 -1.51884649    0.14597201    2.08632626
 C                 -0.25374549   -0.51817699    1.99671826
 C                 -0.18637649   -1.07410299    0.73311126
 O                 -1.35061849   -0.80332099    0.06089426
 H                  0.46591551   -0.67018199    2.78720326
 H                 -1.92856749    0.69604601    2.91866226
 Rh                 1.49619151    0.60076401    0.38816026
 C                  1.66441551    2.09869801   -1.14597574
 C                  2.59011551    2.36960601   -0.09497474
 C                  0.35152351    2.12522201   -0.59829074
 H                  1.93571651    1.79094401   -2.14525074
 C                  1.83196551    2.65653701    1.09995426
 H                  3.66432351    2.33169601   -0.18837174
 C                  0.46763951    2.50200001    0.79520726
 H                 -0.56830949    1.92784601   -1.13074374
 H                  2.24610051    2.87448901    2.07431726
 H                 -0.35404249    2.58950801    1.49201226
 Cl                 3.07483251   -0.42457199    1.97298926
 O                  2.29400586   -0.60634009   -1.05330892
 C                  2.45816642   -1.91681518   -0.81118572
 O                  1.72630017   -2.49199434    0.05888897
 O                  3.29432639   -2.52560587   -1.53455806
 Na                 4.93725900   -1.41937400   -0.06542600
 H                  0.44909851   -1.82965699    0.29394626
 O                 -3.26655849    0.39046201    0.37807026
 C                 -4.32755949   -0.51596799    0.36462626
 O                 -4.24668049   -1.59364299    0.90720726
 N                 -5.38088749   -0.00888099   -0.30357374
 C                 -5.42232349    1.31547101   -0.89759374
 H                 -5.94411649    1.25508101   -1.85702074
 H                 -5.96116349    2.01944501   -0.25215874
 H                 -4.41770049    1.69221001   -1.07439674
 C                 -6.61696749   -0.77001699   -0.32959874
 H                 -7.41177449   -0.22274799    0.18980426
 H                 -6.92744649   -0.94305099   -1.36505774
 H                 -6.46068749   -1.72804899    0.16259026

B 25 22 f

Rh 0
sdd
****
C H O N Cl Na 0
6-31G(d,p)
****

Rh 0
sdd

--link1--
%chk=c5ab-cmda.chk
%CPU=16
%mem=50GB
#p freq wb97xd chkbasis scrf=(smd,solvent=1,4-dioxane) geom=(allcheck,modredundant) guess=read

B 25 22 a