%chk=c3ab-cmda.chk
%CPU=16
%mem=50GB
#p opt=modredundant wb97xd gen scrf=(smd,solvent=1,4-dioxane) pseudo=read

Title Card Required

0 1
 C                  1.09210900   -3.42393300   -1.07269200
 C                  1.18424100   -2.32635100   -1.84307900
 C                  0.13794800   -1.41483600   -1.41227600
 C                 -0.54771300   -2.13107800   -0.43487000
 O                  0.03352600   -3.30550200   -0.19067800
 H                  1.66018600   -4.33609600   -0.98617700
 H                 -0.29570400   -0.61040500   -1.98535700
 O                 -1.64432700   -1.92374600    0.26782100
 C                 -2.65260400   -1.12052700   -0.32870200
 O                 -2.80530300   -1.11724900   -1.52446100
 N                 -3.42444500   -0.54850000    0.60808400
 H                  1.91169700   -2.13325900   -2.61706100
 Rh                 1.10145400    0.03992500    0.16105600
 C                  1.47012600    0.43372900    2.25320000
 C                  2.50827700    0.99504100    1.46182500
 C                  1.44891300   -0.97444700    2.02300900
 H                  0.74128700    1.00372900    2.81046900
 C                  3.19980900   -0.08770800    0.79435200
 H                  2.72142600    2.04877300    1.36316800
 C                  2.55024800   -1.28594300    1.13835400
 H                  0.76975500   -1.68710100    2.46927500
 H                  4.02623400    0.01766100    0.10600400
 H                  2.78633100   -2.26728200    0.75032500
 Cl                 1.57765900    1.45968800   -1.80925900
 O                 -0.78932500    0.75085900    0.18386200
 C                 -1.26736294    1.18589862   -0.99018841
 O                 -0.80224243    0.70175845   -2.07043554
 O                 -2.22932810    2.00504436   -0.94591809
 Na                -0.52100111    3.35067969   -1.59764244
 C                 -4.39058800    0.42634500    0.11327500
 H                 -3.88033700    1.37502900   -0.09339600
 H                 -4.85135000    0.05375300   -0.80104300
 H                 -5.16371400    0.56636700    0.87247500
 C                 -3.00469800   -0.36796700    1.98742900
 H                 -2.49088200    0.59146500    2.10899700
 H                 -3.89122800   -0.39027100    2.62728400
 H                 -2.33540100   -1.16837300    2.29380400

B 7 27 f

Rh 0
sdd
****
C H O N Cl Na 0
6-31G(d,p)
****

Rh 0
sdd

--link1--
%chk=c3ab-cmda.chk
%CPU=16
%mem=50GB
#p freq wb97xd chkbasis scrf=(smd,solvent=1,4-dioxane) guess=read geom=(allcheck,modredundant)

B 7 27 a