%chk=c3ab-cmdb-pre2.chk
%CPU=16
%mem=50GB
#p opt=modredundant wb97xd gen scrf=(smd,solvent=1,4-dioxane) pseudo=read

Title Card Required

0 1
 C                  0.77858500    1.88289000    0.73722300
 C                 -0.34750700    1.17250000    1.12215200
 C                 -1.20878100    2.24024800    1.62893400
 H                 -0.41794625    0.07333524    1.84091912
 Rh                -1.29286400   -0.19675800   -0.40337500
 C                 -3.30161500   -1.01140100   -0.55174400
 C                 -2.76243100   -0.84909600   -1.85666300
 C                 -3.33661400    0.26430900    0.08329200
 H                 -3.53933000   -1.95412800   -0.07857600
 C                 -2.52006300    0.56117000   -2.05803200
 H                 -2.56903700   -1.63587500   -2.57153500
 C                 -2.87725200    1.24195000   -0.87874300
 H                 -3.68640900    0.46093600    1.08644800
 H                 -2.08425000    1.00499300   -2.94198600
 H                 -2.77137200    2.30272200   -0.70102900
 Cl                 0.66001800   -0.56961800   -1.86699200
 O                 -0.61115200   -1.84197600    0.57769700
 C                 -0.30633100   -1.91583400    1.89148900
 O                 -0.64415600   -0.94736500    2.64666800
 O                  1.95801600    1.61783000    0.16165800
 C                  2.58319300    0.40842700    0.28173300
 O                  2.23874300   -0.44687800    1.07871100
 N                  3.65752800    0.34651300   -0.52846700
 C                  4.35843200   -0.92218800   -0.59747900
 H                  4.34417200   -1.40711200    0.37893100
 H                  3.90759000   -1.58336800   -1.35214700
 H                  5.39832400   -0.74380800   -0.87834100
 C                  3.86490900    1.27323300   -1.63247000
 H                  3.57412600    2.28145600   -1.34553200
 H                  4.92751100    1.27769300   -1.88414500
 H                  3.28509900    0.96893900   -2.51132900
 O                  0.65959600    3.19904800    0.90872000
 C                 -0.57653500    3.41411100    1.47158100
 H                 -0.80772400    4.44224800    1.69961400
 H                 -2.17760700    2.09532000    2.08494300
 C                  0.43161983   -3.14103093    2.46238396
 H                  1.44045839   -2.87242856    2.69689947
 H                 -0.06424720   -3.47440729    3.35000780
 H                  0.43138015   -3.92752980    1.73690517

B 2 4 f

Rh 0
sdd
****
C H O N Cl 0
6-31G(d,p)
****

Rh 0
sdd

--link1--
%chk=c3ab-cmdb-pre2.chk
%CPU=16
%mem=50GB
#p freq wb97xd chkbasis scrf=(smd,solvent=1,4-dioxane) guess=read geom=(allcheck,modredundant)

B 2 4 a