%chk=c5ab-sbf-cp-pre.chk
%cpu=16
%mem=50GB
#p opt=modredundant wb97xd scrf=(smd,solvent=dichloroethane) gen pseudo=read 

Title Card Required

0 1
 C                  3.34968100    0.79749600   -1.22893000
 C                  2.62531000    0.71755000   -2.38845900
 C                  1.28322500    0.74369200   -1.96366500
 C                  1.24678400    0.84676400   -0.57494100
 O                  2.58993600    0.88435500   -0.15185800
 H                  0.40403500    0.69708300   -2.59238600
 H                  3.02392800    0.65361000   -3.38935000
 O                  4.67750000    0.88258200   -1.05185800
 C                  5.27296700   -0.18680700   -0.38951400
 O                  4.66418800   -1.21766300   -0.17233800
 N                  6.54218400    0.09523300   -0.06928300
 C                  7.20589000    1.34775400   -0.40419300
 H                  7.94857800    1.55702300    0.36882500
 H                  7.71532600    1.27693700   -1.37139500
 H                  6.49270200    2.16934300   -0.43138700
 C                  7.37496600   -0.95493300    0.49539000
 H                  8.19097600   -1.19758100   -0.19333300
 H                  7.80166400   -0.61749200    1.44443900
 H                  6.77191600   -1.84454300    0.66690000
 H                  0.58237400    1.84749200   -0.02289800
 Rh                 0.03046400   -0.50632200    0.53137200
 C                 -0.03726100   -2.11444200    2.04359100
 C                  1.30455100   -1.70284700    1.69427200
 C                 -0.65445600   -2.59818300    0.88194900
 C                  1.52130800   -2.03714900    0.31288100
 C                  0.29948800   -2.52887100   -0.20608300
 O                 -0.58344000    0.99759900    1.85817300
 C                 -0.58750100    2.23932800    1.60701600
 O                 -0.02321100    2.76393800    0.60181500
 C                 -1.34270700    3.13008700    2.54997600
 H                 -0.93522500    4.14144000    2.53715400
 H                 -2.38174000    3.16570200    2.20726300
 H                 -1.32833900    2.71855900    3.55994500
 F                 -1.55269400    0.43029100   -0.71807000
 Sb                -3.43887200   -0.02673600   -0.51246600
 F                 -3.13677400   -0.63880900    1.25104600
 F                 -5.26331300   -0.44542500   -0.38167100
 F                 -3.63933000    0.58209600   -2.28072800
 F                 -2.98580700   -1.75102600   -1.14358700
 F                 -3.67028400    1.71804700    0.16011600
 C                 -2.12929093   -3.01921435    0.74340464
 H                 -2.74586402   -2.34872475    1.30481474
 H                 -2.41405118   -2.98706677   -0.28750668
 H                 -2.25268011   -4.01438623    1.11664455
 C                 -0.70801389   -1.92013024    3.41615557
 H                 -1.76890915   -2.01122154    3.31078182
 H                 -0.35179116   -2.66569758    4.09596046
 H                 -0.46938375   -0.94846278    3.79538902
 C                  2.35082357   -1.10378612    2.65241592
 H                  1.93841365   -1.04274751    3.63785610
 H                  3.21959692   -1.72821240    2.66740512
 H                  2.62141545   -0.12416797    2.31770961
 C                  2.82521079   -1.77857752   -0.46466534
 H                  3.30000282   -0.89916473   -0.08242762
 H                  3.48090307   -2.61633934   -0.35011075
 H                  2.60068450   -1.64057175   -1.50170071
 C                  0.02969187   -2.93911705   -1.66570906
 H                  0.85188465   -3.51815412   -2.03124305
 H                 -0.86609159   -3.52245576   -1.71248464
 H                 -0.08417314   -2.06178221   -2.26755483

b 20 4 f

Rh sb 0
sdd
****
C H O N F 0
6-31G(d,p)
****

Rh sb 0
sdd

--link1--
%chk=c5ab-sbf-cp-pre.chk
%CPU=16
%mem=50GB
#p freq wb97xd chkbasis scrf=(smd,solvent=dichloroethane) geom=(allcheck,modredundant) guess=read

b 20 4 a