Orca 5.0.3 RELEASE 1 2 3 4 5 6 7 10s8p6d3f1g 15s8p3d2f1g 7s3p2d1f 15s8p3d2f1g 20s14p4d2f1g 15s8p3d2f1g 24s18p10d3f1g 7s5p4d3f1g 7s4p3d2f1g 4s3p2d1f 7s4p3d2f1g 9s6p4d2f1g 7s4p3d2f1g 11s6p5d3f1g 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 Ir C C C C C H H C H H H H C O C C C C C C C C C C C H H H H H H H H H H H H H H H P H N H H C H C H H H C C H Fe C H C H C H C C H C H H C C H H C C C H C H C H C H H C C H C C H C C H H H H C H H H 1 2 2 2 2 2 3 3 2 3 3 3 3 2 4 2 2 2 2 2 2 2 2 2 2 2 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 5 3 6 3 3 2 3 2 3 3 3 2 2 3 7 2 3 2 3 2 3 2 2 3 2 3 3 2 2 3 3 2 2 2 3 2 3 2 3 2 3 3 2 2 3 2 2 3 2 2 3 3 3 3 2 3 3 3 1 Ir ECP Def2-ECP 0 Ir 1 825.5019610000007 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Method DFT(GTOs) Exchange WB97X-V Correlation WB97X-V PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.167000 ScalDFX 0.000000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF Long-range corrected/Screened/Range-Separated Hybrid DFT is turned on Amount of maximum screened exact exchange 0.833000 Range separation parameter mu (erf(mu*r12)/r12) 0.300000 RI-approximation to the Coulomb term is turned on functions 2995 RIJ-COSX (HFX calculated with COS-X)) on IntName me_si_r_wb97xd3bj_ts_sp HFTyp RHF Charge 0 Mult 1 NEL 382 Dim 4321 ENuc 8192.6787927016 Eh CNVDIIS on DIISMaxIt 12 DIISStart 0.200000 DIISMaxEq 15 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 20 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 2.000e-06 Converg. threshold II (energy diff.) 1.000e-09 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF off CNVShift on LevelShift 0.2500 ShiftErr 0.0010 CNVZerner off CNVDamp on DampFac 0.7000 DampMax 0.9800 DampMin 0.0000 DampErr 0.1000 CNVRico off MaxIter 512 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 1.000e-12 Eh TCut 1.000e-14 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-09 Eh 1-El. energy change 1.000e-06 Eh TolErr 1.000e-08 Smallest eigenvalue 6.521e-07 Time for diagonalization 3.485 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 2.772 sec Total time needed 6.354 sec 77 6 6 6 6 6 1 1 6 1 1 1 1 6 8 6 6 6 6 6 6 6 6 6 6 6 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 15 1 7 1 1 6 1 6 1 1 1 6 6 1 26 6 1 6 1 6 1 6 6 1 6 1 1 6 6 1 1 6 6 6 1 6 1 6 1 6 1 1 6 6 1 6 6 1 6 6 1 1 1 1 6 1 1 1 825.5019610000007 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0 1 wB97X-D3BJ def2-QZVP def2/J SP VeryTightSCF defgrid3 SCF MaxIter 512 DIISMaxEq 15 cpcm epsilon 12.47 refrac 1.3878 maxcore 3000 825.5019610000007 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Epsilon 12.4700 Refrac 1.3878 Rsolv 1.3000 Surface type GAUSSIAN VDW Epsilon function type CPCM Ir C H O P N Fe 2.4000 2.0400 1.3200 1.8240 2.1600 1.8600 2.4000 Calculating surface done! ( 0.0s) GEPOL surface points 4663 GEPOL Volume 5463.3767 GEPOL Surface-area 2269.1599 Calculating surface distance matrix done! ( 0.2s) Performing Cholesky decomposition & store done! ( 1.3s) Overall time for CPCM initialization 1.5s -3510.28458878 8192.67879270 -11702.96338148 -21171.83901898 9468.87563750 -0.03501214 -6939.84609456 3429.56150577 2.02353744 190.999937082687 190.999937082687 381.999874165373 -235.312540511216 -16.492119596693 -251.804660107909 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200 201 202 203 204 205 206 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35.3407 35.4143 35.4515 35.4916 35.5441 35.5942 35.6796 35.7621 35.8172 35.8444 35.9091 35.9951 36.0184 36.0734 36.1671 36.1867 36.2221 36.2678 36.3497 36.3602 36.4170 36.5265 36.5815 36.5922 36.6660 36.7131 36.7584 36.7961 36.8690 36.9717 37.0065 37.0565 37.0726 37.1451 37.1891 37.2308 37.3367 37.3545 37.4374 37.5366 37.5518 37.6338 37.6689 37.6797 37.7662 37.7810 37.8556 37.8722 38.0129 38.0546 38.0944 38.1283 38.1930 38.1998 38.3037 38.3658 38.4494 38.5331 38.5571 38.6047 38.6654 38.7278 38.8060 38.9055 38.9299 38.9359 38.9882 39.0438 39.1269 39.2032 39.2777 39.3148 39.3596 39.4558 39.4950 39.5401 39.5819 39.6700 39.7032 39.8256 39.8945 39.9728 40.0063 40.0836 40.1299 40.2012 40.2245 40.3125 40.3953 40.4228 40.5047 40.5577 40.6375 40.6677 40.7225 40.7472 40.7922 40.9882 41.0506 41.1040 41.1366 41.2143 41.2411 41.3128 41.3544 41.4796 41.5390 41.5715 41.6405 41.7052 41.7427 41.8148 41.8698 41.8938 41.9483 42.0169 42.1114 42.1390 42.2001 42.2192 42.3072 42.3549 42.4164 42.4482 42.5780 42.6320 42.6876 42.7048 42.7564 42.7825 42.8448 42.9054 42.9509 42.9709 43.0690 43.1360 43.1804 43.2100 43.2854 43.3636 43.3844 43.4024 43.4569 43.5850 43.6319 43.6755 43.7758 43.8327 43.9298 43.9718 44.0501 44.0813 44.1316 44.2048 44.2702 44.3230 44.3536 44.3806 44.4671 44.5793 44.6010 44.7099 44.7637 44.7750 44.8175 44.8911 44.9056 44.9587 45.0259 45.0801 45.1276 45.1797 45.2179 45.2957 45.4082 45.4836 45.5256 45.6429 45.7114 45.7560 45.8244 45.9444 45.9792 46.0684 46.1131 46.1533 46.2041 46.2698 46.3124 46.3440 46.4306 46.4514 46.5378 46.5625 46.6359 46.7221 46.7610 46.8535 46.9080 46.9681 47.0012 47.0197 47.1023 47.1926 47.2662 47.3142 47.4088 47.4578 47.4996 47.5867 47.6838 47.7163 47.8082 47.9213 47.9892 48.0420 48.0943 48.1109 48.1754 48.3025 48.3912 48.4275 48.5019 48.6038 48.6637 48.6872 48.8120 48.8846 48.8981 48.9290 49.0140 49.1236 49.2107 49.2857 49.3448 49.3851 49.5060 49.5874 49.6034 49.6820 49.7122 49.8760 49.9014 49.9641 50.1327 50.2176 50.2873 50.3125 50.3772 50.3859 50.4791 50.5135 50.6628 50.6915 50.7545 50.8473 50.9266 50.9604 51.0196 51.1385 51.1592 51.2396 51.3068 51.3776 51.4684 51.5527 51.6119 51.6501 51.7127 51.8379 51.9483 51.9786 52.0462 52.0575 52.1601 52.2082 52.2983 52.3360 52.4037 52.5062 52.5704 52.6056 52.6820 52.7134 52.7670 52.8705 52.9259 52.9714 53.0397 53.1178 53.1586 53.2167 53.3113 53.3700 53.4220 53.4828 53.5752 53.6186 53.6645 53.6824 53.8527 53.9345 54.0138 54.0475 54.1009 54.1180 54.2534 54.3455 54.4125 54.4718 54.5122 54.5489 54.6432 54.7185 54.7710 54.8088 54.8792 54.9221 54.9806 55.0632 55.0998 55.1588 55.2500 55.2863 55.3367 55.4304 55.5316 55.5608 55.6087 55.6500 55.7061 55.8231 55.8529 55.9312 55.9523 56.0199 56.0364 56.1282 56.1431 56.1961 56.2784 56.2998 56.3971 56.4829 56.5967 56.6023 56.6877 56.6942 56.7475 56.8275 56.8898 56.9398 57.0418 57.0571 57.1183 57.1500 57.2232 57.2868 57.3656 57.4048 57.4782 57.5660 57.6292 57.7016 57.7366 57.7893 57.8141 57.8740 57.9582 58.0228 58.0444 58.0871 58.2011 58.2681 58.3429 58.3742 58.4507 58.5007 58.5572 58.6074 58.6759 58.7179 58.8010 58.8794 58.9094 58.9300 58.9607 58.9836 59.0537 59.1207 59.1513 59.2100 59.2238 59.2430 59.3605 59.4444 59.5019 59.5505 59.6311 59.6774 59.7173 59.7615 59.7847 59.8035 59.9160 59.9277 59.9983 60.0580 60.1583 60.2093 60.2126 60.2619 60.3391 60.3754 60.3970 60.4520 60.5106 60.5609 60.6412 60.6935 60.7433 60.7947 60.8552 60.8943 60.9907 60.9935 61.0766 61.0844 61.1249 61.1414 61.2887 61.3104 61.3327 61.4059 61.4668 61.5146 61.5354 61.5630 61.6074 61.7110 61.7443 61.7888 61.8443 61.9038 61.9386 62.0054 62.0338 62.0851 62.1237 62.1589 62.2134 62.2801 62.3133 62.3594 62.4117 62.4342 62.4920 62.5877 62.6664 62.6859 62.7010 62.7762 62.8631 62.8713 62.9472 62.9821 63.0571 63.0793 63.1751 63.2557 63.3043 63.3599 63.3883 63.3937 63.4287 63.4395 63.5334 63.5795 63.6436 63.6711 63.7390 63.7920 63.8702 63.9102 63.9337 63.9481 64.0573 64.1025 64.1346 64.1619 64.2132 64.2346 64.2540 64.3173 64.3760 64.4263 64.4602 64.4865 64.5026 64.5937 64.6918 64.7654 64.8069 64.8546 64.8889 64.9257 64.9893 65.0242 65.0392 65.0733 65.1605 65.2262 65.2482 65.2791 65.4222 65.4484 65.4695 65.5434 65.5832 65.6885 65.7082 65.7382 65.7563 65.7960 65.8340 65.9444 65.9831 66.0821 66.1559 66.1697 66.2108 66.2395 66.3098 66.3994 66.4210 66.4414 66.5016 66.6058 66.6342 66.6427 66.7216 66.7859 66.8457 66.9005 66.9413 67.0016 67.0509 67.0961 67.1440 67.1511 67.2179 67.2685 67.2822 67.3772 67.4019 67.4204 67.5375 67.5664 67.6213 67.6503 67.7379 67.8124 67.8551 67.9217 67.9667 68.0266 68.0818 68.1596 68.2205 68.2578 68.3099 68.3482 68.3987 68.4436 68.4939 68.5512 68.5783 68.6302 68.7250 68.7768 68.8142 68.8785 68.9505 69.0087 69.1260 69.1419 69.1632 69.2490 69.3177 69.3372 69.3811 69.4724 69.5068 69.5640 69.6237 69.6839 69.7763 69.8061 69.8409 69.8812 69.8986 69.9216 70.0346 70.0499 70.0871 70.1306 70.1804 70.3138 70.3474 70.3998 70.5180 70.5459 70.6566 70.6727 70.7398 70.7469 70.8190 70.8358 70.9232 70.9392 70.9591 71.0056 71.0681 71.1269 71.1467 71.1575 71.2037 71.3544 71.3896 71.4689 71.5023 71.5282 71.5441 71.6381 71.6631 71.7073 71.7962 71.8654 71.9471 71.9915 72.0422 72.0951 72.1746 72.2513 72.3032 72.3357 72.3728 72.4365 72.4872 72.5691 72.6389 72.6645 72.6965 72.7192 72.7645 72.8626 72.9372 72.9684 72.9990 73.0490 73.0717 73.1572 73.1873 73.2079 73.2956 73.3225 73.4329 73.4536 73.5180 73.5670 73.6325 73.6488 73.7284 73.8070 73.8551 73.8814 73.9275 74.0105 74.0893 74.1020 74.1718 74.2183 74.2684 74.3112 74.3360 74.4915 74.5069 74.5932 74.6693 74.6818 74.7125 74.7929 74.8506 74.8666 74.9186 74.9797 75.0173 75.0815 75.1088 75.2175 75.2343 75.2817 75.2925 75.3746 75.4165 75.4973 75.5550 75.5897 75.6317 75.6802 75.7316 75.7841 75.8354 75.8836 75.9204 76.0165 76.0274 76.0792 76.1205 76.2456 76.2674 76.3169 76.3909 76.4276 76.4477 76.5079 76.5581 76.5752 76.6488 76.6922 76.7500 76.8036 76.8344 76.8484 76.8954 76.9853 77.0088 77.0252 77.1177 77.1517 77.1838 77.2749 77.2991 77.3008 77.3845 77.4699 77.5140 77.5334 77.5963 77.6387 77.7106 77.7300 77.7793 77.8234 77.9038 77.9168 78.0113 78.0984 78.1441 78.1807 78.2161 78.2743 78.3172 78.3832 78.4015 78.4737 78.5257 78.5553 78.6245 78.6471 78.7254 78.7668 78.8128 78.8618 78.9248 78.9536 78.9971 79.0061 79.0794 79.1400 79.1499 79.2190 79.2243 79.2789 79.3619 79.4357 79.4594 79.5544 79.6043 79.6177 79.6438 79.6912 79.7579 79.8099 79.8760 79.9117 80.0182 80.0336 80.1222 80.1717 80.1931 80.2299 80.2877 80.3312 80.3632 80.4050 80.4336 80.5406 80.6317 80.6427 80.6854 80.7969 80.8276 80.8912 80.9380 81.0326 81.0814 81.1254 81.1709 81.2485 81.2779 81.2813 81.3652 81.4553 81.5257 81.5933 81.6469 81.6890 81.7175 81.7756 81.8157 81.8787 81.9019 82.0172 82.0225 82.1032 82.1280 82.1905 82.2371 82.2974 82.3214 82.3523 82.3695 82.4327 82.4700 82.5262 82.6227 82.6556 82.6902 82.8229 82.8569 82.9056 82.9786 83.0189 83.0576 83.0996 83.1819 83.1937 83.2448 83.2994 83.3919 83.4454 83.4994 83.5257 83.6323 83.6788 83.7116 83.8402 83.8805 83.9064 83.9559 84.0189 84.1067 84.1237 84.2604 84.2816 84.3406 84.3804 84.4150 84.4394 84.4970 84.5348 84.5779 84.7019 84.7461 84.8263 84.8659 84.9262 84.9851 85.0631 85.1056 85.1362 85.1879 85.2767 85.3413 85.3577 85.4274 85.4772 85.4813 85.5712 85.6973 85.7446 85.7677 85.8179 85.8822 85.9064 85.9661 86.0596 86.0951 86.1320 86.2425 86.2537 86.3306 86.3849 86.4701 86.4835 86.5128 86.5851 86.6195 86.6821 86.7103 86.7858 86.8251 86.8392 86.9027 87.0221 87.0492 87.1293 87.1860 87.2685 87.3049 87.3874 87.4234 87.4836 87.5258 87.6201 87.7180 87.7387 87.8030 87.8268 87.9216 87.9723 88.0127 88.0603 88.1463 88.2441 88.2850 88.3234 88.3793 88.4146 88.5043 88.6182 88.6769 88.6978 88.7268 88.8540 88.9058 88.9329 88.9594 89.0606 89.0840 89.1559 89.2527 89.3635 89.3948 89.4866 89.5001 89.6011 89.6399 89.6553 89.7218 89.8554 89.8939 89.9830 90.0204 90.0639 90.1060 90.1879 90.2067 90.2451 90.3349 90.4321 90.4678 90.5040 90.5556 90.6156 90.6772 90.7228 90.7637 90.7970 90.8606 90.9905 91.0246 91.0618 91.1478 91.1799 91.2125 91.2235 91.3900 91.4232 91.4871 91.5126 91.6917 91.7519 91.8100 91.8515 91.9320 91.9750 92.0550 92.0794 92.1468 92.1725 92.2764 92.3571 92.4118 92.4561 92.5431 92.5859 92.6789 92.7566 92.7983 92.8538 92.8926 92.9668 93.0435 93.1800 93.2496 93.2749 93.2887 93.4098 93.5271 93.5847 93.6030 93.6742 93.7567 93.8156 93.8229 93.8730 94.0247 94.0909 94.1295 94.1695 94.2187 94.2730 94.3026 94.3901 94.4868 94.5802 94.6816 94.7053 94.7399 94.8649 94.8992 94.9865 95.1108 95.1433 95.1947 95.3150 95.3737 95.3963 95.4817 95.5190 95.5487 95.6241 95.6345 95.7421 95.8192 95.8928 95.9536 96.0559 96.1153 96.1482 96.2361 96.3070 96.3546 96.4084 96.4792 96.5670 96.5902 96.7280 96.7652 96.8062 96.8716 96.9062 97.0557 97.1482 97.1592 97.2697 97.2776 97.3336 97.3675 97.4216 97.5107 97.5450 97.6255 97.7261 97.7790 97.8258 97.9301 98.0357 98.0683 98.1372 98.2651 98.2934 98.3395 98.3866 98.4664 98.5138 98.6218 98.6833 98.7295 98.7809 98.8472 98.8947 98.9781 99.0443 99.1176 99.1937 99.2395 99.3373 99.3677 99.3953 99.4931 99.5783 99.6537 99.7032 99.7886 99.8746 99.9198 99.9680 100.0425 100.1002 100.1572 100.1932 100.2158 100.3707 100.4106 100.5382 100.6424 100.6553 100.7256 100.8302 100.8954 100.9717 101.0254 101.0826 101.1678 101.2027 101.3000 101.3529 101.4319 101.5459 101.6903 101.7097 101.7233 101.7893 101.8109 101.8674 101.9097 102.0685 102.1387 102.2012 102.2636 102.2993 102.3926 102.4072 102.4813 102.5962 102.7692 102.7916 102.8541 102.9680 103.0162 103.0401 103.0716 103.1269 103.1669 103.2326 103.3329 103.3797 103.4399 103.5184 103.5947 103.7426 103.8456 103.9250 104.0549 104.1225 104.1294 104.2097 104.2873 104.3375 104.3539 104.5259 104.6546 104.6686 104.7777 104.8524 105.0181 105.0620 105.1509 105.2255 105.2908 105.3734 105.4044 105.5535 105.5852 105.6786 105.7677 105.8398 105.8840 106.0625 106.1265 106.2286 106.2630 106.3022 106.3987 106.4804 106.5330 106.6549 106.7305 106.7853 106.8876 106.9389 107.0173 107.0447 107.2046 107.2766 107.3059 107.3870 107.4857 107.6007 107.6295 107.7287 107.8134 107.9394 108.0151 108.0863 108.1826 108.2533 108.2624 108.3797 108.4974 108.6493 108.6967 108.7704 108.8228 108.9126 108.9321 109.0154 109.0690 109.1084 109.1670 109.1831 109.3236 109.3929 109.4400 109.5468 109.6321 109.7215 109.7783 109.8402 109.9313 109.9608 110.1097 110.2003 110.3306 110.4120 110.4672 110.4821 110.5894 110.6618 110.7242 110.7958 110.8991 111.0050 111.0250 111.2260 111.2625 111.3338 111.3885 111.4783 111.6023 111.6297 111.7175 111.7925 111.9139 111.9789 112.0488 112.1011 112.1395 112.3307 112.3723 112.3824 112.5740 112.7263 112.7927 112.8706 112.9129 113.0036 113.1842 113.2216 113.3084 113.3350 113.4732 113.5371 113.7243 113.8475 113.9352 114.0204 114.0585 114.2107 114.2677 114.3427 114.4232 114.5104 114.6709 114.7452 114.8171 115.0846 115.1057 115.1804 115.2820 115.3427 115.4621 115.6723 115.7565 115.8115 115.9461 116.0223 116.0443 116.1535 116.2515 116.3057 116.4448 116.6386 116.7844 116.8977 117.0042 117.1433 117.1963 117.2638 117.4410 117.5604 117.6731 117.8179 117.9324 117.9681 118.0836 118.2557 118.4883 118.6462 118.7645 118.9056 119.0227 119.0731 119.2232 119.3379 119.4870 119.6298 119.7108 119.7956 119.9249 120.1378 120.2021 120.3440 120.4666 120.6179 120.7751 121.0067 121.2186 121.2526 121.3887 121.7090 121.8149 122.0247 122.1632 122.2813 122.5405 122.5804 122.8879 122.9894 123.2613 123.3714 123.4402 123.5342 123.6948 123.8515 123.9881 124.0698 124.2138 124.4415 124.5355 124.5904 124.7541 124.9679 125.1658 125.2576 125.3724 125.6140 125.7772 126.0025 126.0550 126.1685 126.3386 126.4246 126.5795 126.6798 126.9392 127.0052 127.1468 127.2701 127.3442 127.5827 127.8776 127.9338 128.0327 128.4103 128.5635 128.6382 128.7875 128.9065 129.1656 129.2349 129.3268 129.4290 129.5823 129.6904 129.7454 129.8757 130.0366 130.3724 130.5256 130.8531 130.9849 131.1307 131.4457 131.6893 131.8540 132.1310 132.2481 132.5104 132.6650 132.9359 133.0069 133.1778 133.3871 133.5133 133.7654 133.8506 133.9447 134.0866 134.2461 134.2821 134.4353 134.5938 134.6284 134.8476 134.9424 135.0362 135.2937 135.4439 135.5495 135.6591 135.8866 136.0633 136.1985 136.2468 136.5492 136.6965 137.0294 137.0910 137.1835 137.3846 137.4342 137.5687 137.6091 137.7698 137.9386 138.0609 138.1137 138.3261 138.4545 138.5870 138.9134 138.9762 139.0625 139.1988 139.2833 139.5065 139.6127 139.7867 139.9470 140.0718 140.1644 140.3557 140.4353 140.6137 140.7400 140.7530 141.0674 141.1108 141.3153 141.3206 141.7350 141.8227 141.9874 142.0378 142.2497 142.3495 142.3937 142.5066 142.6217 142.8365 142.8747 142.9959 143.0469 143.1671 143.2439 143.3538 143.5224 143.6863 143.7794 143.8122 143.9164 143.9658 144.0823 144.2488 144.3025 144.3817 144.4646 144.4864 144.6117 144.6789 144.8906 144.9270 144.9462 145.0615 145.2155 145.3499 145.4016 145.4486 145.4557 145.5573 145.8070 145.8394 145.9166 145.9912 146.1514 146.2556 146.3566 146.6016 146.6186 146.8103 146.8450 146.8685 146.9216 147.0478 147.1825 147.1930 147.3801 147.4030 147.4649 147.5750 147.8163 147.9057 147.9554 148.0446 148.1116 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