Orca 5.0.4 RELEASE 1 2 3 4 5 6 15s10p3d1f 5s1p 12s7p2d1f 12s7p2d1f 12s7p2d1f 15s10p3d1f 6s6p2d1f 3s1p 6s4p2d1f 6s4p2d1f 6s4p2d1f 6s6p2d1f 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 S S H N N O O C C C C C C C C C C N N C N C C N C C H H H H H H H H Cl 1 1 2 3 3 4 4 5 5 5 5 5 5 5 5 5 5 3 3 5 3 5 5 3 5 5 2 2 2 2 2 2 2 2 6 395.7824999999999 AuxInfo=1/0/N:9,11,10,13,12,14,8,15,25,17,23,16,26,20,22,35,5,4,19,21,18,24,7,6,2,1/E:(8,9)(10,11)(12,13)(14,15)(17,18)(19,20)(21,22)(23,24)(25,26)/CRV:1.3,2.3,3.3,4.3,5.3,6.3,8.3,9.3,10.3,11.3,12.3,13.3,14.3,15.3,19.2,20.2,21.2,22.2,23.1,24.1,25.1,26.1/rA:35nS1S1HNNO1O1CC3C3C3C3C3C3C3C3C3N2N2C3N2C3C3N2C3C3HHHHHHHHCl/rB:;;;;;;;;s9;s3s9;s8s10;s11;s12s13;s8;s7s15;s5s15;s16;s17;s2s18s19;;s1s21;s4s21;s22;s8s23;s6s24s25;s4;s4;s5;s5;s8;s9;s10;s13;s14;/rC:4.2118,-2.495,-3.6556;-5.767,.7894,-.7076;1.5153,.3915,5.1525;.1485,-3.7774,-1.0972;-.9028,1.5886,-.0324;1.5597,.7807,-1.0525;-2.4518,-2.8982,-.4547;-.2134,-1.3115,.2622;1.8685,.4059,3.0148;1.4253,-.0201,1.7722;1.1788,.0596,4.1707;.2701,-.797,1.6089;.0397,-.7218,4.0523;-.3929,-1.136,2.7973;-1.5748,-.7323,-.1051;-2.6528,-1.6464,-.3821;-1.8862,.6201,-.1781;-3.9127,-1.1475,-.565;-3.1288,1.0864,-.3869;-4.1032,.1693,-.5325;1.988,-3.0444,-2.2728;2.8442,-2.0602,-2.5991;1.024,-2.7338,-1.3932;2.7158,-.7948,-2.2109;.8678,-1.4773,-.8052;1.7144,-.4508,-1.3474;.246,-4.4881,-1.808;-.8277,-3.4879,-.9324;.0096,1.319,-.4371;-1.2553,2.4665,-.3866;-.497,-2.3414,.507;2.7641,1.0224,3.0743;1.9405,.2873,.8663;-.5277,-1.0274,4.9271;-1.8089,-2.144,2.7656; Method DFT(GTOs) Exchange PBE PBE kappa parameter XKappa 0.804000 XMuePBE 0.219520 Correlation PBE PBE beta parameter CBetaPBE 0.066725 LDAOpt PW91-LDA PostSCFGGA off Hybrid DFT is turned on ScalHFX 0.250000 ScalDFX 0.750000 ScalDFC 1.000000 ScalLDAC 1.000000 Perturbative correction 0.000000 Density functional embedding theory OFF NL short-range parameter 6.900000 RI-approximation to the Coulomb term is turned on functions 5780 RIJ-COSX (HFX calculated with COS-X)) on IntName 3g-f-anion_SP HFTyp RHF Charge -4 Mult 1 NEL 210 Dim 982 ENuc 2747.7973897172 Eh CNVDIIS on DIISMaxIt 0 DIISStart 0.200000 DIISMaxEq 5 DIISBfac 1.050 DIISMaxC 10.000 CNVTRAH auto Auto Start mean grad. ratio tolernc. 1.125000 Auto Start start iteration 1 Auto Start num. interpolation iter. 10 iterations 16 iterations Maxiter - #DIIS iter Number of Davidson start vectors 2 Converg. threshold I (grad. norm) 1.000e-05 Converg. threshold II (energy diff.) 1.000e-08 Micro threshold 0.100 Minimum threshold for Micro iter. 0.010 NR start threshold (gradient norm) 0.001 Initial trust radius 0.400 Minimum AH scaling param. (alpha) 1.000 Maximum AH scaling param. (alpha) 1000.000 Orbital update algorithm Taylor David. guess on Maximum white noise 0.010 Quad. conv. algorithm NR CNVSOSCF on SOSCFMaxIt 150 SOSCFStart 0.001000 CNVShift on LevelShift 0.2500 ShiftErr 0.0000 CNVZerner off CNVDamp on DampFac 0.9200 DampMax 0.9800 DampMin 0.0000 DampErr 0.0030 CNVRico off MaxIter 125 SCFMode Direct Integral package SHARK and LIBINT hybrid scheme DirectResetFreq 20 Thresh 2.500e-11 Eh TCut 2.500e-12 Eh ConvCheckMode Total+1el-Energy ConvForced 0 TolE 1.000e-08 Eh 1-El. energy change 1.000e-05 Eh TolG 1.000e-05 TolX 1.000e-05 TolErr 5.000e-07 Smallest eigenvalue 1.773e-08 Time for diagonalization 0.133 sec Threshold for overlap eigenvalues 1.000e-08 Number of eigenvalues below threshold 0 Time for construction of square roots 0.144 sec Total time needed 0.280 sec PBE0 ma-def2-TZVP D4 AutoAux TightSCF VerySlowConv FREQ %basis PCDTrimAuxJ Coulomb PCDTrimAuxC Coulomb PCDTrimAuxJK Coulomb PCDThresh -1 end -4 1 pal nproc 22 end %maxcore 10000 #%scf # DirectResetFreq 2 # DIISMaxEq 40 0.00 0.00 0.00 0.00 0.00 0.00 27.42 37.40 44.43 63.45 66.00 110.48 115.82 138.29 143.73 169.68 176.90 199.17 205.67 218.76 225.02 228.31 248.77 262.51 290.39 320.47 332.52 372.40 382.49 400.33 434.68 445.87 477.59 496.69 532.08 543.95 547.19 558.86 571.38 590.41 618.80 623.37 631.98 669.71 703.56 707.08 713.28 724.51 737.55 740.45 752.27 772.67 814.09 829.40 841.49 854.57 880.70 891.04 897.74 903.12 956.50 958.94 988.03 1061.47 1066.37 1078.50 1085.05 1110.49 1124.25 1141.54 1170.83 1189.33 1199.37 1206.80 1240.84 1268.34 1282.93 1307.96 1323.93 1327.62 1337.45 1391.75 1399.00 1413.44 1462.26 1476.20 1487.06 1499.61 1515.94 1527.26 1573.39 1586.15 1595.47 1635.01 1677.99 1684.93 3042.71 3114.84 3130.12 3140.58 3162.38 3166.41 3169.81 3595.98 3602.27 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 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