# geometry optimized at the PBE0/def2-TZVP/D4/SMD level
! wB97M-V def2-TZVPPD VeryTightSCF AIM SMD(acetonitrile)
%pal nproc 22 end
%maxcore 10000
*xyzfile 0 1 AlCl-CO2_SMD-MeCN.xyz