%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

ts

1 1
  C           3.44752529314842     -2.79045727126029     -0.63627125912189
  C           3.87358353546082     -1.47737677367629     -0.90812946991489
  C           2.98693778408031     -0.41883242540158     -0.80476643136845
  C           1.65672877281973     -0.66622924057180     -0.42073127311764
  C           1.21940564624530     -1.97479302311146     -0.14827441954942
  C           2.11340082135093     -3.02668741471961     -0.25591177238188
  H           4.91005583116422     -1.29885799604693     -1.19887773413850
  H           3.31964842949371      0.60002890357511     -1.01385318076907
  H           0.18559495720090     -2.16141183833960      0.15020462474138
  H           1.79005299979220     -4.04697924692097     -0.04346317532958
  C           0.74528456483092      0.43432189421908     -0.29186192057657
  H          -0.02981042518575      0.78719440726960     -1.24773176783382
  C          -0.83934179691274      2.54241693930021      0.17162389664017
  C          -2.08618437491254      2.34263096306096      0.79214425746291
  C          -0.39635795782141      3.83386559189357     -0.16856313367515
  C          -2.88336900467286      3.44366329265664      1.07320440720200
  H          -2.41503243085399      1.33478596785844      1.05442692408361
  C          -1.20705189620701      4.92281062264790      0.12006493335918
  H           0.57523203536883      3.97421257159927     -0.64729793604576
  C          -2.44466382812491      4.72656314401128      0.73741348478554
  H          -3.85146708229539      3.30436789214334      1.55795850880354
  H          -0.87508752531745      5.93073453769269     -0.13579650014008
  H          -3.07738271995413      5.58832264545622      0.96244631151887
  C           0.00156737545053      1.41513249341806     -0.10044555113009
  C           4.36849833488786     -3.88292648607188     -0.74624587764897
  C           5.14542516948542     -4.80464678406016     -0.83989764580562
  H           5.83750065147803     -5.62525796662182     -0.92423374004980





