%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.10885177   -0.32871760    0.15396421
 N                  0.14915680    0.80608218   -0.07643989
 C                 -1.60588890    0.06733333   -0.59301123
 H                 -1.55514856   -0.75384266   -1.31569582
 H                 -1.60766633    1.00062122   -1.16112743
 H                  0.11554016   -1.30784208    0.55703808
 O                  2.28269248   -0.00018205    1.04976527
 H                  3.06380791   -0.04644144    0.46069739
 H                  2.60293711    0.35741682    1.88319033
 O                  4.40183130   -0.16729101   -0.68882803
 H                  4.83212172    0.59209617   -1.09232685
 H                  5.05480809   -0.87283431   -0.66594046
 O                 -2.60009956    0.01787178    0.43363316
 C                 -3.88613035   -0.18806044   -0.15680458
 H                 -4.62866588   -0.23284617    0.61230869
 H                 -4.10793376    0.62181390   -0.81998388
 H                 -3.88406578   -1.10723819   -0.70453445

