%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

ts

1 1
 C                  0.31105715    0.80270140    0.21550452
 N                  0.76181586    1.33339062   -0.75370474
 C                 -1.13580670    1.12252562   -0.59111880
 H                 -1.63428657    1.48008005    0.32017288
 H                 -1.15262477    1.93096601   -1.32581511
 O                  2.97566951    0.87172191    0.33769657
 H                  3.48483024    0.19940681   -0.15847783
 H                  3.56967787    1.61685866    0.46525387
 O                  4.24972632   -1.13102399   -1.05074196
 H                  4.52136208   -1.05626985   -1.97040634
 H                  4.86980191   -1.73587249   -0.63268927
 C                  0.38336949    0.11547866    1.54016487
 H                  0.89657561   -0.84264727    1.36609875
 H                  1.03743771    0.74271129    2.16333803
 O                 -0.91150881   -0.01496452    2.01624521
 C                 -0.97326819   -0.58461288    3.32650403
 H                 -0.45198114    0.05318305    4.04853942
 H                 -2.02955430   -0.64085257    3.58132672
 H                 -0.53894710   -1.59026121    3.33022672
 C                 -1.65549795   -0.19070825   -1.16368015
 F                 -2.92897363    0.09081683   -1.60009289
 F                 -1.72275919   -1.15572072   -0.22201840
 F                 -0.90329180   -0.58945292   -2.21138650