%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  1.15328966    0.13879732   -0.52631635
 N                  1.41885217    0.91266290    0.33776739
 C                 -0.33062421    0.92058529   -0.44612863
 H                 -0.38096635    1.24157971   -1.49263040
 H                 -0.39715591    1.82538991    0.17057660
 H                  1.39836623   -0.67817181   -1.19611748
 O                  3.67367060   -0.38354434    0.06480121
 H                  4.44811706    0.06946919   -0.28633024
 H                  4.00905404   -0.94566392    0.77164637
 C                 -1.34557636   -0.12111785    0.04014746
 F                 -2.55015561    0.52732878   -0.01620502
 F                 -1.08671645   -0.48949205    1.31285796
 F                 -1.39215900   -1.20033419   -0.76955751

