%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  0.45920444   -0.29505927   -0.04582686
 N                  0.67445221    0.80630630   -0.44141215
 C                 -0.93298089   -0.09726731   -0.96681423
 H                 -0.81239686   -0.99623538   -1.58181523
 H                 -0.97606049    0.75521463   -1.65435603
 H                  0.72097686   -1.17575260    0.53072741
 O                  2.72350434    0.12606286    1.02205579
 H                  3.54856015    0.01259957    0.50462948
 H                  2.98824438    0.53486283    1.85164533
 O                  4.94310407   -0.21892592   -0.54179968
 H                  5.40614993    0.50660590   -0.97097817
 H                  5.58915222   -0.92028698   -0.41667355
 C                 -2.10883799   -0.05181504    0.01241223
 F                 -3.22341669   -0.04132827   -0.78540198
 F                 -2.07033284    1.07637573    0.75281951
 F                 -2.15324738   -1.14098056    0.80880803

