%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

ts

1 1
 C                  0.17949453    0.41993879   -0.45144850
 N                  1.24348955    0.95400168   -0.58279263
 C                  0.04699071    0.63134228   -2.12815650
 H                 -0.90407431    1.17275728   -2.10216230
 H                  0.78937057    1.29937952   -2.57046392
 O                  1.78657691    0.88388958    1.73804218
 H                  1.78401632    0.02319545    2.19441455
 H                  2.62549104    1.31527151    1.92382193
 O                  0.99927341   -1.57761120    2.75040579
 H                  1.51878565   -2.37977322    2.86623263
 H                  0.43109422   -1.51554805    3.52624634
 C                 -0.83418841   -0.21537325    0.41246468
 H                 -1.64103543   -0.63547835   -0.19056546
 H                 -0.31313985   -1.01950668    0.94855958
 C                 -1.37783519    0.78918981    1.44776387
 H                 -2.01513091    1.54578441    0.98306620
 H                 -0.55886430    1.25639546    1.99752590
 F                 -2.14738294    0.05100891    2.32313899
 C                  0.05605915   -0.74556901   -2.74895100
 H                  1.04517639   -1.20279603   -2.68244872
 H                 -0.68628463   -1.41446374   -2.30952008
 F                 -0.24036806   -0.58996759   -4.05678092





