%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.10828004   -0.64599926    0.37058977
 N                  0.20060775    0.34134097   -0.19135956
 C                 -1.42706196   -0.04197152   -0.73961141
 H                 -1.46204084   -0.87782444   -1.44590541
 H                 -1.41775973    0.91494417   -1.27831400
 H                 -0.18629205   -1.55700947    0.97414883
 O                  2.22249790    0.13346353    1.22446093
 H                  2.88020953    0.10313997    0.49868524
 H                  2.38878451    0.97576648    1.66212338
 O                  4.04775573    0.03097710   -0.79428551
 H                  3.99530953   -0.33155468   -1.68479652
 H                  4.92459200   -0.21367702   -0.47907356
 C                 -2.51791817    0.00553610    0.34637927
 H                 -2.50609565   -0.90761584    0.90397570
 H                 -2.33022643    0.82789276    1.00471150
 F                 -3.72591146    0.16173715   -0.23573193

