%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.37744241   -0.38963919    0.25317751
 N                  0.08242215    0.44978543   -0.43233715
 C                 -1.51262863    0.10359220   -1.09019770
 H                 -1.56007591   -0.84226156   -1.63959214
 H                 -1.35470919    0.94141707   -1.78235780
 H                 -0.60527817   -1.16508554    0.99282799
 O                  1.92270082    0.34463238    1.22238872
 H                  2.64306664    0.12905427    0.59401492
 H                  2.12751717    1.23696936    1.52315258
 O                  3.92046958   -0.27243916   -0.52276157
 H                  3.92110312   -0.78700769   -1.33664644
 H                  4.73291411   -0.52429680   -0.07048104
 C                 -2.69596275    0.43678275   -0.16267173
 H                 -3.06333451    1.44017274   -0.10657781
 C                 -3.27360199   -0.53648335    0.58274965
 H                 -3.02499021   -1.56341139    0.41389764
 H                 -3.98071660   -0.27710866    1.34275865

