%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

ts

1 1
 C                  0.08027932    1.95411854    0.20272164
 N                  0.91627548    2.85768453    0.18237042
 C                 -1.15286517    2.98306450    0.21585933
 H                 -1.66276848    2.70098377    1.14267746
 H                 -0.81623791    4.01488903    0.35451728
 O                  2.81451810    2.05356640    0.15418786
 H                  3.26609703    2.73846717   -0.35661920
 H                  3.14360013    2.13022250    1.05981424
 C                 -1.95321217    2.83417671   -1.06796379
 H                 -1.35882030    3.13307833   -1.93416472
 H                 -2.31556952    1.81650487   -1.21884968
 H                 -2.81342218    3.50632605   -1.00337510
 C                 -0.08152473    0.50844272    0.18999611
 C                 -1.27991010   -0.05905545    0.64947222
 C                  0.95413383   -0.30493114   -0.29769359
 C                 -1.43359220   -1.43738034    0.63452941
 H                 -2.08633887    0.56073685    1.02604459
 C                  0.77783163   -1.68171072   -0.32096404
 H                  1.87444814    0.13840152   -0.65485661
 C                 -0.40836597   -2.24702271    0.14542379
 H                 -2.35432817   -1.87997659    0.99720967
 H                  1.56851430   -2.31575179   -0.70600259
 O                 -0.57822019   -3.66660976    0.11675073
 C                  0.59510299   -4.27616025   -0.42791515
 H                  1.44678797   -3.99479660    0.15549482
 H                  0.48567364   -5.34038287   -0.40906222
 H                  0.73078810   -3.94939829   -1.43772512





