%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  0.12138324   -0.03480840   -0.43427996
 N                  0.35889437    0.74246193    0.43468242
 C                 -1.41994339    0.58523684   -0.20687238
 H                 -1.61338828    1.00194484   -1.19624644
 H                 -1.58005277    1.35900147    0.55084458
 H                  0.39656498   -0.79909158   -1.15212830
 O                  2.70692363   -0.29376439    0.01925526
 H                  3.41867500    0.23940570   -0.35116826
 H                  3.12367676   -0.83733046    0.69669266
 C                 -2.17728445   -0.69181316    0.20200148
 H                 -1.99181310   -1.46214251   -0.51709035
 H                 -1.83958008   -1.01390946    1.16486685
 H                 -3.22666450   -0.48668807    0.24231549

