%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.72139914   -0.61225076    0.29251000
 N                 -0.37285124    0.38087331   -0.23499203
 C                 -1.98826064    0.04552988   -0.84721298
 H                 -2.01622952   -0.77287934   -1.57395154
 H                 -1.94048963    1.01417817   -1.36239556
 H                 -0.83910667   -1.53502692    0.87124838
 O                  1.59424376    0.09682192    1.24340323
 H                  2.27582383    0.06903150    0.53989008
 H                  1.76281324    0.92503127    1.70635843
 O                  3.48551790    0.00148047   -0.71399272
 H                  3.45629089   -0.33922245   -1.61413552
 H                  4.34568410   -0.26924759   -0.37505838
 C                 -3.11470067    0.09155034    0.20188900
 H                 -3.14110580   -0.83424745    0.73770728
 H                 -2.93276920    0.89427735    0.88557773
 H                 -4.05288310    0.24659635   -0.28869683

