%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.31907177   -0.01711691   -0.85523498
 N                  0.55259686    0.35916390   -1.58250941
 C                 -0.99013911   -0.37704939   -2.37106209
 H                 -1.12631206   -1.45356252   -2.26652497
 H                 -1.89052076    0.23560532   -2.32762679
 H                 -0.44741893   -0.16412777   -3.29323154
 O                  1.85420199    1.04331560    0.40648396
 H                  2.63527790    0.47538471    0.56174719
 H                  2.18192893    1.94640947    0.37519998
 O                  3.95698488   -0.67394975    0.87049573
 H                  4.69329466   -0.83033343    0.27216827
 H                  4.28699541   -0.83819356    1.75873953
 C                 -0.97231682   -0.27504833    0.44289450
 H                 -0.92849526   -1.35786507    0.60479708
 H                 -0.30135381    0.20861990    1.16020615
 O                 -2.31354870    0.21564027    0.51515599
 C                 -2.96948417   -0.13087415    1.74564757
 H                 -2.44107557    0.30601066    2.59937965
 H                 -3.96641151    0.29689274    1.67088914
 H                 -3.03912111   -1.21850397    1.85126680

