%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  0.22110894   -0.05760593   -0.84656130
 N                  1.05508513    0.44313292   -1.54230970
 C                 -0.46569686   -0.28306559   -2.38118839
 H                 -0.54384531   -1.37028515   -2.39526094
 H                 -1.39514206    0.27176766   -2.25386505
 H                  0.04371670    0.05945954   -3.28310395
 O                  2.36577216    0.97184179    0.48769043
 H                  3.17843175    0.43299147    0.56486856
 H                  2.64579590    1.88913979    0.55182520
 O                  4.56434130   -0.67079698    0.72014409
 H                  5.29357739   -0.72021875    0.09534341
 H                  4.92297158   -0.91438469    1.57857835
 C                 -0.38757720   -0.49234887    0.42579777
 H                 -0.28435737   -1.58250624    0.46488032
 H                  0.27415256   -0.05571431    1.18086484
 C                 -1.84698982   -0.05652688    0.58646950
 F                 -2.26700002   -0.43744180    1.81162061
 F                 -1.97734252    1.28446007    0.50125118
 F                 -2.65419915   -0.64515767   -0.32151007

