%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.50737219    0.61184796   -0.15569081
 N                 -0.54392285    1.77160568    0.15906419
 C                 -2.15030856    0.69963952    0.00961805
 H                 -2.48290867    0.43054706   -0.99376213
 H                 -2.32722536   -0.03784634    0.79335471
 H                 -2.59877010    1.65267022    0.29928686
 O                  1.79181168    2.12673273    0.07907435
 H                  2.03928031    2.80298055   -0.56106654
 H                  2.13126448    2.43387672    0.92692488
 C                  0.24837448   -0.60418346   -0.54159608
 H                 -0.03135657   -0.83304357   -1.57579818
 H                  1.29548205   -0.28930111   -0.52280299
 C                 -0.02420324   -1.79435926    0.38480173
 H                 -1.06042113   -2.13499849    0.32305268
 H                  0.21943828   -1.55785331    1.42267862
 F                  0.76547115   -2.81775576   -0.00452326

