%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.33769871   -0.03191416   -0.82630510
 N                  0.50758359    0.38922236   -1.56010575
 C                 -1.03815075   -0.35234031   -2.33769804
 H                 -1.14881708   -1.43464194   -2.26893952
 H                 -1.94999222    0.23832548   -2.25064294
 H                 -0.52298059   -0.09474440   -3.26426232
 O                  1.84302453    1.03065656    0.42067535
 H                  2.63957402    0.47495666    0.53659890
 H                  2.15063195    1.94131491    0.41425450
 O                  3.99259773   -0.65515536    0.77192501
 H                  4.71708237   -0.77380223    0.15091889
 H                  4.34782588   -0.84361647    1.64551267
 C                 -0.95310791   -0.35032223    0.47687780
 H                 -0.88232654   -1.43698781    0.59842113
 H                 -0.27507969    0.12218696    1.19498302
 C                 -2.39807350    0.14023938    0.60751142
 H                 -3.06885653   -0.37068765   -0.08753207
 H                 -2.47137782    1.21927252    0.45662484
 F                 -2.82350686   -0.13379091    1.85907598

