%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.38039456   -0.04024822   -0.77445118
 N                  0.45587011    0.37255899   -1.52316551
 C                 -1.09813845   -0.37968265   -2.27353175
 H                 -1.20697948   -1.46115059   -2.19027113
 H                 -2.00945538    0.21127779   -2.18305106
 H                 -0.59405976   -0.13302266   -3.20912826
 O                  1.81373680    1.03922019    0.43389735
 H                  2.61210594    0.48561253    0.54728611
 H                  2.12039399    1.94997636    0.41276122
 O                  3.96884357   -0.64046200    0.78057532
 H                  4.68614168   -0.76611496    0.15264344
 H                  4.33442035   -0.81794773    1.65219018
 C                 -0.98025263   -0.34319175    0.53962392
 H                 -0.90703821   -1.42823375    0.67359540
 H                 -0.29433264    0.13859934    1.24393453
 C                 -2.43202170    0.15049000    0.68190849
 C                 -3.17258946   -0.10046630    1.75271826
 H                 -2.80426354    0.72723518   -0.17540291
 H                 -4.20793946    0.25159178    1.85418186
 H                 -2.80034631   -0.67720812    2.61003136

