%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.60360332    0.14803539   -0.14365172
 N                 -0.83282086    1.22908775    0.29730341
 C                 -2.26322453    0.00699277    0.05031345
 H                 -2.56972805   -0.17555330   -0.98054059
 H                 -2.31017483   -0.82471191    0.75448558
 H                 -2.82817773    0.85398298    0.45270278
 O                  1.74447631    1.34395423   -0.02502759
 H                  2.13018208    1.93459158   -0.68111639
 H                  2.32640528    1.40106305    0.74058716
 C                  0.33339013   -0.94363932   -0.69309652
 H                 -0.23256377   -1.63802275   -1.27826985
 H                  1.08657101   -0.49248771   -1.30471796
 C                  1.00091637   -1.68524158    0.47994859
 H                  0.24718657   -2.05516944    1.14323191
 H                  1.57709300   -2.50410971    0.10262184
 H                  1.64227005   -1.01171443    1.00902952

