%nprocshared=8
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                 -0.43125240   -0.08778800   -0.00252384
 N                 -0.36095893    1.09994299   -0.00572487
 C                 -2.06881340    0.27306706    0.00344841
 H                 -2.38086174   -0.20068817   -0.92827544
 H                 -2.37072778   -0.19304720    0.94226713
 H                 -2.38514424    1.32111942    0.00178427
 O                  2.15343589    0.43864936    0.00213309
 H                  2.71079850    0.62317750   -0.76165367
 H                  2.70286863    0.63211547    0.76944216
 C                  0.17772926   -1.50226260   -0.00081034
 H                  0.78469738   -1.62820286    0.87132999
 H                 -0.60780335   -2.22877542    0.00338869
 H                  0.77941722   -1.63259339   -0.87595917

