%nprocshared=12
%mem=22GB
#p opt=(calcfc,ts,noeigentest,maxstep=7) freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

ts

1 1
 C                 -0.83529509    0.45940067    0.00005590
 N                  0.08292515    1.23394186   -0.00134454
 O                  1.78027090   -0.42261010    0.00024911
 H                  2.36053051   -0.36016655   -0.76644823
 H                  2.35740731   -0.36233640    0.76951581
 C                 -1.37778043   -0.90773454   -0.00041635
 H                 -0.52773635   -1.59213541   -0.00263423
 H                 -1.99228906   -1.05201078    0.89166155
 H                 -1.99722996   -1.05042415   -0.88928354
 H                 -1.74487252    1.85036432    0.00677021