%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.79371579103694     -5.29969114573110      0.09205594507851
  C          -0.43610753366233     -4.66672131583398      1.29251455068682
  C           0.13625623384118     -3.41266298795512      1.25224085668197
  C           0.35628980110628     -2.77576966001039     -0.01100786558155
  C          -0.01853694221471     -3.44271556563956     -1.22112256892502
  C          -0.58913166561663     -4.69671589210779     -1.15873543328913
  H          -0.60913706166444     -5.16651268116008      2.24717562497954
  H           0.42741487131055     -2.89063375594771      2.16660192708750
  H           0.15432019344372     -2.94398782329586     -2.17749996321158
  H          -0.87976614666616     -5.21981855321822     -2.07146757647345
  C           0.91728427084272     -1.52914693368033     -0.05941432189520
  H           2.58337906496662     -0.44191866976093     -0.16623660177813
  C           0.90123239414490      0.98145515583460     -0.07133671531127
  C          -0.48367200399229      1.18446363370205      0.00128578684961
  C           1.75276915426030      2.10050034429230     -0.11648574836787
  C          -1.01689679551016      2.46441063279264      0.02796572920394
  H          -1.16514388260744      0.32913787798901      0.03705877001460
  C           1.23251054353750      3.37892911688603     -0.08976692045296
  H           2.83593241247486      1.96412606298073     -0.17344528077043
  C          -0.15873265031395      3.57835850065377     -0.01796935076058
  H          -2.09804801371448      2.59056241174993      0.08461835128167
  H           1.87847437069653      4.25776070626436     -0.12329224421087
  C           1.48439711758694     -0.36184065342109     -0.10001549172387
  H          -1.24666804201733     -6.29432717478966      0.13249506801186
  O          -0.56818654693123      4.84355735594287      0.00080739217395
  C          -1.94729847728165      5.14280754058950      0.06774096330621
  H          -2.02553313219839      6.23530642621163      0.06532662154347
  H          -2.48581408900782      4.74071400048934     -0.80572627195597
  H          -2.39630144377613      4.75109790617306      0.99493907780824





