%nprocshared=8
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024)

opt freq

1 1
 C                  1.10684080   -0.42118140   -0.14760038
 N                  2.05458003    0.32042662   -0.55068003
 O                  3.31532760   -0.01755030    0.37353476
 H                  4.01534209   -0.30737586   -0.24354464
 H                  3.59358902    0.83968338    0.75069524
 C                 -0.18698889   -0.30102477   -0.88633656
 H                 -0.37746705   -1.28092610   -1.34283136
 H                 -0.11556115    0.44243853   -1.68369662
 H                  1.21581295   -1.11736506    0.68553958
 C                 -1.35061432    0.03133401    0.06105417
 F                 -2.50338907   -0.02845702   -0.68398366
 F                 -1.23320684    1.27783238    0.56598714
 F                 -1.44693991   -0.86424267    1.06662058

