%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -1.08427955993214     -5.11987591027532      0.08152614485168
  C          -0.51920566923695     -4.60621935061054      1.26024822308937
  C           0.27316717004617     -3.48070489730768      1.19627840844104
  C           0.50628677718652     -2.85360323686100     -0.07201819559699
  C          -0.08370263333374     -3.39706157980624     -1.26064205841118
  C          -0.87249260388264     -4.52330429545995     -1.17216705585469
  H          -0.70712137713794     -5.09783684353688      2.21632817596152
  H           0.72794325703142     -3.05314298283281      2.09280558484917
  H           0.10128739253722     -2.90619716954441     -2.21886978853835
  H          -1.32942373180109     -4.95187698858043     -2.06584555664324
  C           1.27926974398746     -1.73314607509196     -0.14830701391448
  H           3.09246785346309     -0.90548856307794     -0.40102665090254
  C           1.62771241611979      0.74017702927826     -0.13655130096650
  C           0.29458479612236      1.09892819964827      0.10582250046769
  C           2.60122917208196      1.73191744521132     -0.29345754694162
  C          -0.05300633142930      2.43909711071881      0.18618273423257
  H          -0.47777465125511      0.33740441220419      0.23877040688484
  C           2.24302301865904      3.07574096397648     -0.20936296154765
  H           3.64216608473056      1.45786473384800     -0.48256991087078
  C           0.92031958470837      3.43163976927762      0.03060473439977
  H           3.00361956922400      3.84914283023899     -0.33180488271548
  C           2.02732344556783     -0.67725345421024     -0.23214234559828
  H          -1.71031216554039     -6.01481774375857      0.14129872664599
  C          -1.49402847055160      2.84189149396505      0.41382504055200
  F          -1.58692441932163      3.77293855276764      1.36028533620806
  F          -2.02648550201867      3.34156983599054     -0.70137340802896
  F          -2.23896681524652      1.79621205151739      0.78704695352726
  H           0.63812098922191      4.48460627231138      0.10152166641978





