%nprocshared=8
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
 C                  0.33079876    1.00909261    0.04553556
 N                  1.57115439    1.10258031    0.33319652
 O                  2.35220032   -0.05479220   -0.33917030
 H                  3.28304076    0.13948737   -0.12618386
 H                  2.07204008   -0.91656378    0.05823336
 C                 -0.49815326    2.10093914    0.64907536
 H                 -1.27344555    1.64679259    1.27396893
 H                  0.10474970    2.78419180    1.24697385
 C                 -0.33066058   -0.05752068   -0.79534065
 H                 -1.31177795    0.29526948   -1.11908433
 H                  0.26342250   -0.28560991   -1.68442067
 C                 -0.55035405   -1.34855917   -0.01374109
 F                 -1.13197556   -2.27021395   -0.75678604
 F                 -1.25751478   -1.15116635    1.09349731
 F                  0.66911146   -1.86981835    0.39466815
 C                 -1.18890557    2.87922525   -0.48614796
 H                 -2.13059932    2.42302965   -0.70975131
 H                 -1.34712657    3.89201832   -0.17936416
 H                 -0.56892888    2.86338477   -1.35808717





