%nprocshared=8
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
 C                  0.70035819    0.19662065    0.13375603
 N                  1.91516570   -0.16396603    0.27056153
 O                  2.05991249   -1.71304063   -0.19972484
 H                  2.70650815   -1.68463693   -0.92924114
 H                  2.49663193   -2.14537603    0.55752169
 C                  0.54382746    1.63370494    0.56779005
 H                 -0.10342176    1.66630759    1.44924207
 H                  1.50094477    2.09505125    0.81223185
 C                 -0.47556925   -0.56521984   -0.39379595
 H                 -0.68133959   -0.16702896   -1.39586982
 H                 -0.25051417   -1.62642668   -0.49551668
 C                 -1.73732785   -0.39850959    0.46457092
 H                 -2.09712481    0.63369652    0.47492217
 H                 -1.57418228   -0.74466336    1.48999673
 F                 -2.71073744   -1.18650671   -0.10651810
 C                 -0.13370071    2.41771276   -0.57145853
 H                 -1.18833109    2.46162066   -0.39616777
 H                  0.26365388    3.41057325   -0.60663498
 H                  0.05282521    1.92567681   -1.50312838





