%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.82895496375159     -5.70803417464315      0.07154525066471
  C          -0.48648816698117     -5.08527558310470      1.28110522655253
  C           0.08176488265641     -3.82820090935214      1.25853353448264
  C           0.31392953912559     -3.17794825300653      0.00554082247314
  C          -0.04564854277107     -3.83476733818493     -1.21342845943015
  C          -0.61297611460933     -5.09175039025485     -1.17020330222987
  H          -0.66794397083322     -5.59450783077320      2.22919214432700
  H           0.36086164198028     -3.31372990265863      2.18084918292620
  H           0.13579876150980     -3.32576207453121     -2.16272264403672
  H          -0.89202768058620     -5.60626964223218     -2.09139082796376
  C           0.87234629761959     -1.92702011207956     -0.02491130510120
  H           2.54076300030909     -0.84902945183715     -0.10125887260170
  C           0.87784638316252      0.58481351605907     -0.01669939002041
  C          -0.50935626409718      0.81464393353675      0.04063430384598
  C           1.73326286423604      1.69878612244750     -0.04281333568326
  C          -1.02168407237928      2.09359221392938      0.06824878956818
  H          -1.20524266390146     -0.02977310058697      0.06381697303188
  C           1.23570086892798      2.98635021950545     -0.01428963678177
  H           2.81632828528568      1.55387831370500     -0.08659287224735
  C          -0.16298812628880      3.22959749305438      0.03947662349473
  H          -2.10231629433549      2.22052042230294      0.11361394000579
  H           1.93992911947263      3.81657368501067     -0.03558579192296
  C           1.44146551802077     -0.75770163385430     -0.04798856224486
  H          -1.27869739871636     -6.70454235872694      0.09736615997294
  N          -0.66183195471262      4.49199836300492      0.06201642422166
  C           0.23560994164663      5.63169946317971      0.04416161596911
  C          -2.09435464723909      4.71316339107650      0.11584493681598
  H          -0.35364403039212      6.55502539322090      0.05890552995252
  H           0.90022110600802      5.64263280826692      0.92409649109985
  H           0.85891127479710      5.64618852218322     -0.86521277711643
  H          -2.29364714642640      5.79017942071323      0.10703889284140
  H          -2.60799232228131      4.27043082982247     -0.75348202682391
  H          -2.53977269445546      4.29642701480743      1.03473678195812





