%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.53051927609577     -5.36828365595861      0.28406270205805
  C           0.06358495452111     -4.71396069946454      1.37590840277393
  C           0.56319061767273     -3.44050397008549      1.21191194405416
  C           0.46883115876542     -2.80580306908358     -0.07107723456352
  C          -0.14019670553602     -3.49705713284909     -1.17070808685787
  C          -0.63448383820111     -4.76908844953870     -0.98213628315972
  H           0.12625897628659     -5.21361717607499      2.34420014287068
  H           1.03172860538348     -2.90270288322581      2.03937530788326
  H          -0.20323585235801     -3.00016677602382     -2.14159456324847
  H          -1.10362564583351     -5.30901213454727     -1.80646853030867
  C           0.94440339532251     -1.54061474785409     -0.24335161717991
  H           2.47462213473056     -0.33639857322776     -0.72684358286295
  C           0.72998060004124      0.95028972695592     -0.26596280558289
  C          -0.61912545413977      1.01552738569071      0.10909297111848
  C           1.45634590500368      2.12057327131369     -0.50779308215972
  C          -1.22596528479942      2.25320700445671      0.23732068287164
  H          -1.22001015143794      0.12532103657059      0.30645306905357
  C           0.82743910506388      3.35129771253406     -0.37267865543429
  H           2.50744890218595      2.10632621040772     -0.80164040758318
  C          -0.51410192954763      3.43332833791983     -0.00082024478202
  C           1.41609421377220     -0.34514689470354     -0.41951046012565
  H          -0.92606380027395     -6.37840400943950      0.42431496255320
  F          -2.49355491024710      2.34165254525288      0.58743386871309
  F          -1.10247976594366      4.59878512857949      0.12404015912351
  F           1.49185717566454      4.46624191239527     -0.59650593922471





