%nprocshared=8
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
 C                 -0.45609590    1.44761670   -0.00066365
 N                  0.38830946    2.40129048    0.00321611
 O                  1.89089291    1.76817475    0.00486702
 H                  2.31327767    2.16456681   -0.77928670
 H                  2.30972249    2.16486861    0.79077110
 C                 -1.86006185    2.00207589   -0.00635686
 H                 -2.37208749    1.62738209   -0.89684160
 H                 -2.37952175    1.62692702    0.87962047
 H                 -1.87679153    3.09219795   -0.00616401
 C                 -0.24599865   -0.07798450   -0.00030366
 C                 -0.14537783   -0.76851736   -1.20840599
 C                 -0.15618857   -0.76942004    1.20775229
 C                  0.04433413   -2.15026665   -1.20836034
 H                 -0.21699309   -0.22321867   -2.16064671
 C                  0.03456718   -2.15145553    1.20797570
 H                 -0.23529405   -0.22530486    2.16001801
 C                  0.13469830   -2.84195468    0.00020019
 H                  0.12302567   -2.69470692   -2.16056249
 H                  0.10575274   -2.69630045    2.16063034
 H                  0.28433896   -3.93140590   -0.00001353





