%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.07705025377890     -3.77341262324690     -0.04564830531381
  C           0.29274156376119     -3.12470344402628      1.15074075100763
  C           0.61964294425618     -1.78670815757240      1.11721798191520
  C           0.58029362558590     -1.07636581121007     -0.12325864676797
  C           0.20296285244772     -1.75553900049867     -1.32384188613571
  C          -0.12263339566577     -3.09357030781012     -1.28041556878689
  H           0.31568333002052     -3.68611044857288      2.08626240101594
  H           0.90917683343585     -1.25653962597182      2.02724113159010
  H           0.17698826181022     -1.20197962422377     -2.26511381488654
  H          -0.41335355609136     -3.63164144892138     -2.18419237668624
  C           0.89318521194797      0.25664920780316     -0.15937718701111
  H           2.29780543478077      1.65849999662027     -0.38005332340692
  C           0.37666627690480      2.70818491097888     -0.04111359229971
  C          -1.00237828518182      2.60339760775022      0.19889376419181
  C           0.97938729174243      3.96855326920991     -0.13720114110485
  C          -1.76646636403977      3.75355024512444      0.33978567645748
  H          -1.47960957263929      1.62196419294344      0.27593856276112
  C           0.20592801714973      5.11722088827690      0.00504552941562
  H           2.05311577836247      4.05380140571205     -0.32306305510827
  C          -1.16286666438405      5.01027235567777      0.24243080789175
  H          -2.83939673289250      3.67354559920669      0.52596193839786
  H           0.67601614948389      6.09976386960254     -0.07036334686722
  H          -1.76770218092952      5.91304180679622      0.35281441807994
  C           1.21899678993427      1.50987866847089     -0.19845713506466
  C          -0.41946380987600     -5.16971906339595     -0.00537814567908
  N          -0.69642075614493     -6.29155432872321      0.02721504239454





