%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.08662485748770     -3.76373425441338      0.01130593617460
  C           0.29234134900500     -3.08897516474153      1.19965937122349
  C           0.62594478305962     -1.75863146479541      1.15302629763730
  C           0.59090880106867     -1.05286648058753     -0.09602193319233
  C           0.20526844793677     -1.75033435862625     -1.28950759974961
  C          -0.12661279244205     -3.08062268991468     -1.23081426501451
  H           0.31389886945404     -3.64002749370551      2.14110521826332
  H           0.92006957176720     -1.22087217096761      2.05715724740911
  H           0.18101886997000     -1.20655338650109     -2.23654955295326
  H          -0.42157407752243     -3.62556905682880     -2.12883328886247
  C           0.91277905125613      0.26853397718027     -0.14659289379765
  H           2.31824553703295      1.68373819195242     -0.38232418457257
  C           0.38631960793194      2.71293668697598     -0.04789445409890
  C          -0.99114980897278      2.59660915860790      0.19269169379122
  C           0.97327617665472      3.97974279377888     -0.15101115195794
  C          -1.76830864948947      3.73929613483358      0.32699931271677
  H          -1.45724686768539      1.61028749640439      0.27514847300559
  C           0.18795364650731      5.12149141109270     -0.01545303965296
  H           2.04610893336222      4.07525082885493     -0.33736812585501
  C          -1.17953872443129      5.00213337843206      0.22258391937172
  H          -2.84035455931304      3.64807021246411      0.51353866871730
  H           0.64805284402143      6.10837573557627     -0.09661378831705
  H          -1.79412302921496      5.89893637052444      0.32771172626069
  C           1.24344135226085      1.52226411995850     -0.19829093631807
  C          -0.43190503139734     -5.14294627517365      0.06543603504261
  C          -0.72629364164124     -6.31643328149616      0.11098913294155
  H          -0.98875296169117     -7.36143606888481      0.15059370178708





