%nprocshared=12
%mem=22GB
#p opt freq=noraman wb97xd 6-31+g(d,p) nosymm scf=(xqc,maxcyc=1024) 

opt freq

1 1
  C          -0.02151090745016     -3.57995890974252      0.22320783079691
  C           0.64147348896042     -2.86821601992104      1.26874477783816
  C           0.94699701684941     -1.55211822810480      1.10723474916640
  C           0.60362812097453     -0.86667410782260     -0.11745593160374
  C          -0.06776749644184     -1.60612716363340     -1.15600766143128
  C          -0.37404236467986     -2.92797746090939     -0.99427049354110
  H           0.88771953578411     -3.41641291093942      2.17948667291967
  H           1.45562866397892     -0.99616607180040      1.89796114470840
  H          -0.32946686380246     -1.08740699320594     -2.08124821008926
  H          -0.88176195826705     -3.47198976176994     -1.79060126055046
  C           0.89657349434083      0.43990159045286     -0.29421793373155
  H           2.17917504406832      1.85810289389212     -0.94184694926657
  C           0.37606244486096      2.87948272090660     -0.16502244527108
  C          -0.87305561736524      2.76303666679750      0.46287383593411
  C           0.86822247277086      4.14489614381686     -0.50570160011622
  C          -1.61737770354117      3.90152624370367      0.74267474205826
  H          -1.26221909798579      1.77826350822717      0.73774907600077
  C           0.11689408391522      5.28308170387521     -0.22382161162204
  H           1.84146782790771      4.24108468122416     -0.99406349820408
  C          -1.12352428691472      5.16231473346017      0.39868506536676
  H          -2.58887093835528      3.80920373752708      1.23282262079045
  H           0.50310481915382      6.26828779493334     -0.49312112017743
  H          -1.71184845509053      6.05554507602675      0.62029139272948
  C           1.19222034648358      1.69218324232485     -0.48319938918202
  O          -0.26716472958610     -4.83218300584871      0.46954276229544
  C          -0.91772063979707     -5.68183038667956     -0.47819709754034
  H          -0.32509782884154     -5.74985033959540     -1.40164281646539
  H          -0.97468776065945     -6.66537661866126     -0.00233374178640
  H          -1.93167380127042     -5.31388545853394     -0.69073587002583





